O$2(35\%).$ Although not used commercially, the Daniell cell illustrates the thermodynamics of

cell operation and is a useful learning tool.

Calculate $E$ and $G$ for the cell

Plot ${}_{+-}$data as a function of concentration ranging from $0\mathrm{.}001$ to $1m$ for aqueous

CuSO$4$ and ZnSO$4$ and fit the trend line using power law function

The initial condition of the cell is $m_{ZnS{O}_4}=m_{CuS{O}_4}=0\mathrm{.}1m.$ Plot cell emf during

discharge using $m_{ZnS{O}_4}$ as the x$-$axis to the limit of $m_{ZnS{O}_4}$

On this same chart plot the ideal emf$(a=m)$ and compare the ideal emf with the actual

emf