Problem $3$

The rate and equilibrium constant can be obtained as a function of the reference

temperature $(T_F)$ s

$k_i=k_{k_i{r}_i}$exp$[-\frac{E_i}{R}(\frac{1}{T}-\frac{1}{T_r})]s^{-1}$

$K_i=K_{k,r_i}$exp$[-\frac{H_i}{R}(\frac{1}{T}-\frac{1}{T_r})]$

where:

$i=$ reactions $1,2,3$

$i=C{O}_2{H}_2,Ci{H}_4,H_{2}O$

The data in the table below were obtained by Xu and Froment. ${?}^8($FONTE$)$

$)$ and bar