Table 1. Acidities and structure of the carboxylic acids of interest. Note that each acid contains...
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Table 1. Acidities and structure of the carboxylic acids of interest. Note that each acid contains the same protic bond....an 0-H bond. Acid Formic acid Acetic acid Chloroacetic acid Dichloroacetic acid Structure TV 0: H-C101H ww 0: H- H H 0: [[]][C] [COH C 0: Įdo T pka 3.75 4.75 2.85 1.48 Trichloroacetic acid Benzoic acid Procedure +0. E Pivalic acid 4 * R O ii do 5 D Part A Build each acid from Table 1, each in their own sheet of your Spartan document. Do not compute or adjust them. Simply use the build function and create each species. T Cl- Each of the acids under investigation are part of the Spartan Library, so the name of each acid should appear at the bottom of the sheet. If you click on the name, a dialogue box appears that displays the library level of computation available. That is, the computations we seek are already complete and we can utilize them directly, without going through the submission of computation steps. 6 HC- Cl Y CH 0: CH, 0: 7 2 -H 13 # $.0 140 8 1 9 0.7 4.19 5.03 bb1 O 0 S P br For your conclusion to the above exploration, discuss the trends you see in acid strength based upon the structure of the acid. Table 1. Acidities and structure of the carboxylic acids of interest. Note that each acid contains the same protic bond....an 0-H bond. Acid Formic acid Acetic acid Chloroacetic acid Dichloroacetic acid Structure TV 0: H-C101H ww 0: H- H H 0: [[]][C] [COH C 0: Įdo T pka 3.75 4.75 2.85 1.48 Trichloroacetic acid Benzoic acid Procedure +0. E Pivalic acid 4 * R O ii do 5 D Part A Build each acid from Table 1, each in their own sheet of your Spartan document. Do not compute or adjust them. Simply use the build function and create each species. T Cl- Each of the acids under investigation are part of the Spartan Library, so the name of each acid should appear at the bottom of the sheet. If you click on the name, a dialogue box appears that displays the library level of computation available. That is, the computations we seek are already complete and we can utilize them directly, without going through the submission of computation steps. 6 HC- Cl Y CH 0: CH, 0: 7 2 -H 13 # $.0 140 8 1 9 0.7 4.19 5.03 bb1 O 0 S P br For your conclusion to the above exploration, discuss the trends you see in acid strength based upon the structure of the acid.
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