Question: The definition of compressibility factor Z, Eq. (3.32), may be written in the more intuitive form: V ZE V(ideal gas) where both volumes are

The definition of compressibility factor Z, Eq. (3.32), may be written in

The definition of compressibility factor Z, Eq. (3.32), may be written in the more intuitive form: V ZE V(ideal gas) where both volumes are at the same T and P. Recall that an ideal gas is a model substance comprising particles with no intermolecular forces. Use the intuitive definition of Z to argue that: (a) Intermolecular attractions promote values of Z < 1 (b) Intermolecular repulsions promote values of Z > 1 (c) A balance of attractions and repulsions implies that Z 1. (Note that an ideal gas is a special case for which there are no attractions or repulsions.) Equation (3.32) PV ZE RT =

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