Question: The neutral complex [Co(PPh 3 )(NCS) 2 ] was recently published by the group of Cyril Rajnk et. al. along with its magnetic properties. B=0.11
The neutral complex [Co(PPh3)(NCS)2] was recently published by the group of Cyril Rajnk et. al. along with its magnetic properties.
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B=0.11 T-20K 40 100 150 300 3 0 10 20 30 50 200 250 TIK BT a. Calculate the theoretical magnetic moment by use of the spin-only equation, (Hot = (n(n+2))1/2). (5 pts) b. It was published in the article: The susceptibility taken at B = 0.1 T has been corrected for the underlying diamagnetism and transformed to the effective magnetic moment calculated as Hen/ We = 798(XT)"? (SI units). Estimate the value used to make this correction at 40 K. (10 pts) C. Does the Magnetization vs Field plot reaches saturation? If so, at what temperature? (5 pts) d. From the M vs field plot, explain the variation in the curves at different temperatures. Can one assume that the complex has two magnetic states? (5 pts) field B=0.11 T-20K 40 100 150 300 3 0 10 20 30 50 200 250 TIK BT a. Calculate the theoretical magnetic moment by use of the spin-only equation, (Hot = (n(n+2))1/2). (5 pts) b. It was published in the article: The susceptibility taken at B = 0.1 T has been corrected for the underlying diamagnetism and transformed to the effective magnetic moment calculated as Hen/ We = 798(XT)"? (SI units). Estimate the value used to make this correction at 40 K. (10 pts) C. Does the Magnetization vs Field plot reaches saturation? If so, at what temperature? (5 pts) d. From the M vs field plot, explain the variation in the curves at different temperatures. Can one assume that the complex has two magnetic states? (5 pts) field
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