Question: Two samples A and B sharing the same empirical formula of C 9 H 1 0 O 2 , were examined with 1 H NMR

Two samples A and B sharing the same empirical formula of C9H10O2, were
examined with 1H NMR and electrospray mass-spectrometry (negative mode). The results are as follows.
A.1H NMR \delta , ppm: 12.1(s),1H; 8.09(d),2H; 7.03(d),2H; 2.72(q),2H; 1.18(t),3H.
ESI-MS(-) Parent peak m/z 149 fragmenting (MS2): m/z 105.
B.1H NMR \delta , ppm: 8.06(d),2H; 7.55(dd),2H; 7.68(t),1H; 4.30(q),2H; 1.30(t),3H.
ESI-MS(-) Parent peak m/z 149 fragmenting (MS2): m/z 121; 77. Determine the structure of both compounds.

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