Using the grandcanonical ensemble for a system of constant volume in contact with a heat bath and

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Using the grandcanonical ensemble for a system of constant volume in contact with a heat bath and a particle bath prove the fluctuations in the number of molecules is related to the isothermal compressibility as

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Physical Chemistry

ISBN: 978-0321812001

3rd edition

Authors: Thomas Engel, Philip Reid

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Posted Date: Jan 09, 2021 02:46 AM

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Using the grandcanonical ensemble for a system of constant volume in contact with a heat bath and

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Statistical Physics Section 3 Fluctuations and Response 3 1 Fluctuations in the energy of an assembly Let us consider the Canonical Ensemble The internal energy of an assembly fluctuates randomly abou... View the full answer

Physical Chemistry

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