In fact, pure PbO may show an anti-Schottky disorder. What differences does this bring to the results

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In fact, pure PbO may show an anti-Schottky disorder. What differences does this bring to the results of Problem 3.6?

Problem 3.6

Consider pure PbO with anion-Frenkel compensation and dominant ionic defects. What are the slopes of the essentially linear dependences in the three limiting regions of the plot of defect fractions versus p_O2 ? Sketch the Brouwer diagram.

Brouwer diagram

VNI h ionic defects dominate reduction [v]= [VNI stoichiometric range oxidation h Ni electronic defects

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Solid State Materials Chemistry

ISBN: 9780521873253

1st Edition

Authors: Patrick M. Woodward, Pavel Karen, John S. O. Evans, Thomas Vogt

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Question Posted: Jan 22, 2024 06:45 AM

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In fact, pure PbO may show an anti-Schottky disorder. What differences does this bring to the results

Question:

VNI h ionic defects dominate reduction [v]= [VNI stoichiometric range oxidation h Ni electronic defects dominate reduction [e] = [h*] stoichiometric range h oxidation

Step by Step Answer:

As shown in Figure 31 the intrinsic antiSchottky disorder means that cation and an...View the full answer

Solid State Materials Chemistry

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