Devise a procedure for separating a mixture of the four stereoisomers of isoleucine into its four components:

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Devise a procedure for separating a mixture of the four stereoisomers of isoleucine into its four components: (+)-isoleucine, (-)-isoleucine, (+)-alloisoleucine, and (-2)-alloisoleucine (Problem 31). (Note: Alloisoleucine is much more soluble in 80% ethanol at all temperatures than is isoleucine.) 


Data From Problem 31.

The abbreviation allo means diastereomer in amino acid terms. Draw allo-l-isoleucine, and give it a systematic name. 



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Organic Chemistry structure and function

ISBN: 978-1429204941

6th edition

Authors: K. Peter C. Vollhardt, Neil E. Schore

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