Look up the molar enthalpy of combustion H c (T 0 )and Gibbs free energy of combustion

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Look up the molar enthalpy of combustion ΔHc(T0)and Gibbs free energy of combustion ΔGc(T0) for hydrogen under standard conditions. Notice that |ΔHc(T0)| > |ΔGc(T0)|, suggesting that one might be able to extract more than |ΔGc| from combustion of hydrogen at high temperature, contradicting the claim that the energy of a fuel is |ΔGc(T0)|. Suppose that the hydrogen is combusted isothermally at temperature Tin an engine that runs at the Carnot limit in an environment at T0. Assume for simplicity that ΔHc and ΔSare independent of temperature. Show that the maximum amount of work that can be extracted from such an engine is in fact Wisothermal (TM) = |ΔGc(T0)| and find the temperature TM at which the engine must run to reach this limit.

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The Physics of Energy

ISBN: 978-1107016651

1st edition

Authors: Robert L. Jaffe, Washington Taylor

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