In this chapter, several examples of a current density in one direction inducing the gradient of an

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In this chapter, several examples of a current density in one direction inducing the gradient of an intensive quantity in another direction were shown. These effects are referred to by the name of their discoverers: Righi-Leduc (11.29), Hall (11.75), Nernst (11.85), Ettingshausen (11.80). The latter refers to a temperature gradient induced by an orthogonal electric charge current density. It was pointed out recently that this effect can occur in a crystal, which consists of two types of electric charge carriers and presents a strong crystalline anisotropy in the plane where the heat and electric charge transport take place. No magnetic induction field needs to be applied orthogonally in order to observe this effect [191]. The material has two types of electric charge carriers, electrons (e) and holes (h). Assume that no ‘chemical reaction’ takes place between them. The thermoelectric properties are isotropic, i.e. the same in all directions. Therefore, the Seebeck tensors for the electrons and holes are given by,imageHowever, the conductivities differ greatly in two orthogonal directions. Therefore, the conductivity tensors are given by,imagewhere a and b label the a-axis and the b-axis that are orthogonal crystalline axes. Consider an electric charge transport along the x-axis at an angle θ from the a-axis and show that this electric current density jq induces a heat current density jQ along the y-axis. This is the planar Ettingshausen effect. It can be understood by establishing the following facts:a) Show that the Seebeck tensor for this crystal is given by [176],imageb) Show that the Seebeck tensor for this crystal is diagonal and written as,imagewhere the diagonal component εaa is different from εbb in general. The matrix is given here for a vector basis along the crystalline a-axis and b-axis.


c) Write the components of the Seebeck tensor with respect to the coordinate basis (x, y),imagein terms of the diagonal components εaa and εbb of the Seebeck tensor with respect to the coordinate basis (a, b).d) The heat current density jQ is related to the electric charge current density jq by,image which is a local version of the Peltier effect (11.108). The Peltier tensor is related to the Seebeck tensor by,imageIn particular, for an electric charge current density jq = jq,x ˆx, where ˆx is a unit vector along the x-axis, show that the component jQ,y along the y-axis of the heat current density jQ = jQ,x ˆx + jQ,y ˆy, where ˆy is a unit vector along the y-axis, is given by,imageThus, the planar Ettingshausen effect is maximal for an angle θ = π/4.

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Principles Of Thermodynamics

ISBN: 9781108426091

1st Edition

Authors: Jean-Philippe Ansermet, Sylvain D. Brechet

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