Suppose Ãgn = (ngn. Let the eigenfunctions gn be expanded in terms of the complete orthonormal set

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Suppose Âgn = (ngn. Let the eigenfunctions gn be expanded in terms of the complete orthonormal set {(i} according to
8. = Exc{

Substitute this expansion into

Suppose Âgn = (ngn. Let the eigenfunctions gn be expanded

Multiply by (*i, integrate over all space, and show that the set of equations

Suppose Âgn = (ngn. Let the eigenfunctions gn be expanded

For i = 1, 2, 3, ( ( ( is obtained, where

Suppose Âgn = (ngn. Let the eigenfunctions gn be expanded

This set of equations has the same form as the set (8.53) with Sik = (ik. Thus, just as the W values and the coefficients ck in (8.53) with Sik = (ik can be found by finding the eigenvalues and eigenvectors of the H matrix, the eigenvalues an of  and the expansion coefficients ck(n) k of the eigenfunctions gn of  can be found by finding the eigenvalues an and eigenvectors c(n) of the matrix A, whose elements are Aik.

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Quantum Chemistry

ISBN: 978-0321803450

7th edition

Authors: Ira N. Levine

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