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The enthalpy of vaporization of a certain liquid is found to be 14.4 k] mol' at 180 K, its normal boiling point. The molar volumes of the liquid and the vapour at the boiling point are 115 cm3 mol-1 and 14.5 dm3 mol-1 respectively.

(a) Estimate dp/dTfrom the Clapeyron equation and

(b) The percentage error in its value if the Clausius-Clapeyron equation is used instead.

(a) Estimate dp/dTfrom the Clapeyron equation and

(b) The percentage error in its value if the Clausius-Clapeyron equation is used instead.

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