Question: The reaction between ethyl iodide and hydroxide ion in ethanol (C2H5OH) solution, C2H5I(alc) + OH (alc) -- C2H5OH(I) + I(alc), has an activation energy of

The reaction between ethyl iodide and hydroxide ion in ethanol (C2H5OH) solution, C2H5I(alc) + OHˉ (alc) --→ C2H5OH(I) + Iˉ(alc), has an activation energy of and a frequency factor of 2.10 × 1011 M-1 s-1.
(a) Predict the rate constant for the reaction at 35 oC.
(b) A solution of KOH in ethanol is made up by dissolving 0.335g KOH in ethanol to form 250.0 mL of solution. Similarly, 1.453 g of C2H5I is dissolved in ethanol to form 250.0 mL of solution. Equal volumes of the two solutions are mixed. Assuming the reaction is first order in each reactant, what is the initial rate at 35 oC?
(c) Which reagent in the reaction is limiting, assuming the reaction proceeds to completion?
(d) Assuming the frequency factor and activation energy do not change as a function of temperature, calculate the rate constant for the reaction at 50 oC?

Step by Step Solution

★★★★★

3.52 Rating (176 Votes )

There are 3 Steps involved in it

1 Expert Approved Answer

Step: 1 Unlock

a 1n k E a RT 1n A Ea 868 kJmol 868 10 4 Jmol T 35 o C 273 308 K A 210 1... View full answer

Question Has Been Solved by an Expert!

Get step-by-step solutions from verified subject matter experts

Step: 2 Unlock

Step: 3 Unlock

Document Format (1 attachment)

876-E-C-E-E-C (600).docx

120 KBs Word File

Students Have Also Explored These Related Chemical Engineering Questions!

Draw the transition state for the reaction between ethyl iodide and sodium acetate

(a) Give the structure of the S*2 reaction product between ethyl iodide and potassium acetate. H,C-C potassium acetate

A certain reaction has an activation energy of 54.0 kJ/ mol. As the temperature is increased from 22oC to a higher temperature, the rate constant increases by a factor of 7.00. Calculate the higher...

Problem 14.110 1 of 8 The reaction between ethyl iodide and hydroxide ion in ethanol (CH OH) solution, CHI(alc) + OH (ale)-C,H,OH(1) +I (alc), has an activation energy of 86,8 kJ/mol and a frequency...

predict the rate constant for the reaction at 41C The reaction between ethyl iodide and hydroxide ion in ethanol (C2H5OH) solution, C2H5I(alc) + OH (alc)+CH,OH(1) +I (alc), has an activation energy...

please explain the hard soft acid base theory behind the reaction. is ethyl iodide hard or soft? is ethyl tosylate hard or soft? how does the hardness/ softness of the reactants, effect the...

Reaction of ethyl iodide with triethylamine yields a crystalline compound C8H20NI in high yield. This compound is soluble in polar solvents such as water but insoluble in nonpolar ones such as...

Reaction of ethyl iodide with triethylamine [CH3H2)3N:] yields a crystalline compound C8H20N in high yield. This compound is soluble in polar solvents such as water but insoluble in non polar ones...

6. Dyashkovskii and Shilov [Kinetics and Ca- talysis, 4 (808), 1963] have studied the kinetics of the reaction between ethyl lithium and ethyl iodide in decalin solution. C2H5Li+C2H51 2C2Hz: + Lil...

A reaction was done in which sodium saccharin and DMF reacted with either ethyl iodide or ethyl tosylate in an RBF with water. Next ethyl acetate was added and then the organic layer was extracted....

Review the following 2012 balance sheet and income statement for T. F. Baker Cosmetics Inc. appear below. The numerical values are in thousands of dollars. At a recent board meeting, the firm decided...

Derive g V h from the premises b b A c, (b + c) (hv g) Derive the following, using rule CP if necessary, (p V q) r (p ^ q) r

1 6 . 1 4 The following data have been reported for a sample of 1 0 major U . S . zoological parks: x 3 5 Number y 5 x 1 5 x 2 5 of City Budget Attendance Acres Species 1 $ 1 9 . 5 million 0 . 6...

Jill is focusing on advertising. Choose another medium of marketing communication to announce the formation of the new company and its position (instead of advertising). Then defend your decision. If...

The sluice gate in Fig P3.63 can control and measure flow in open channels. At sections 1 and 2, the flow is uniform and the pressure is hydrostatic. The channel width is b into the paper. Neglecting...

Water at 20°C exits to the standard sea-level atmosphere through the split nozzle in Fig P3.62 Duct areas are A1 = 0.02 m2 and A2 = A3 = 0.008 m2. If p1 = 135 kPa (absolute) and the flow rate is...

The 6-cm-diameter 20°C water jet in Fig P3.64 strikes a plate containing a hole of 4-cm diameter. Part of the jet passes through the hole, and part is deflected. Determine the horizontal force...

KADS, Inc., has spent $420,000 on research to develop a new computer game. The firm is planning to spend $220,000 on a machine to produce the new game. Shipping and installation costs of the machine...

1) An exporter has just received a banker's acceptance created by an international transaction. If the banker's acceptance has a face value of $250,000 and the bank charges a commission of 1% per...

Problem #7 Refer to Problem 6 (listed below). Assume that another alternative is a convertible mortgage (instead of a participation loan) that gives the lender the option to convert the mortgage...