Using Table 6.1, write an equation for each of the following substitution reactions: a. p-methylbenzyl chloride +
Question:
a. p-methylbenzyl chloride + sodium acetylide
b. n-propyl bromide + sodium cyanide
c. 2-iodopropane + sodium hydrosulfide
d. 1-bromopentane + sodium iodide
e. 2-chlorobutane + sodium ethoxide
f. t-butyl bromide + ethanol
g. 1,6-dibromohexane + sodium cyanide (excess)
h. allyl chloride + ammonia (2 equivalents)
i. 1-methyl-1-chlorocyclohexane + water
Transcribed Image Text:
Table 6.1 Reactions of Common Nucleophiles with Alkyl Halides (Eqs. 6.2 and 6.3) Nu Formula Oxygen nucleophiles 1. HO,-hydroxide R-Nu ame Formula Comments alcohol ether alkyloxonium ion .RO alkoxide R OR .. R-0 These ionsROH lose a proton and the products are alcohols and ROR 3. нон (alcoho) 4. ROH alcohol dialkyloxonium ion ether) 0 carboxylate ester Nitrogen nucleophiles alkylammonium ion With a base, RNH NH ammonia these ions readily lose a proton to give amineS. RNH2 primary amine R-NH,R dialkylammonium ion RNH condary amine R-NHR trialkylammonium ion tertiary amine R-NR tetraalkylammonium ion Sulfur nucleophiles 10. HS: 11. RS: 12. RS: Halogen nucleophiles 13. hydrosulfide RSH mercaptide R-SR thioether thiol thioether (sulfide) trialkylsulfonium ion R-SR The usual solvent is acetone. Sodium iodide is soluble in acetone, but sodium bromide and sodium chloride are not. iodide R-I: alkyl iodide Carbon nucleophiles 14. C N: Sometimes the isonitrile R-N C:, is formed. cyanide R-C-N: alkyi cyanide (nitrile) 15. :C CR acetylide R-C-CR alkyne
Fantastic news! We've Found the answer you've been seeking!
Step by Step Answer:
Answer rating: 88% (9 reviews)
Each of these reactions involves displacement of a halogen ...View the full answer
Answered By
PALASH JHANWAR
I am a Chartered Accountant with AIR 45 in CA - IPCC. I am a Merit Holder ( B.Com ). The following is my educational details.
PLEASE ACCESS MY RESUME FROM THE FOLLOWING LINK: https://drive.google.com/file/d/1hYR1uch-ff6MRC_cDB07K6VqY9kQ3SFL/view?usp=sharing
3.80+
3+ Reviews
10+ Question Solved
Related Book For
Organic Chemistry A Short Course
ISBN: 978-1111425562
13th edition
Authors: Harold Hart, Christopher M. Hadad, Leslie E. Craine, David J. Hart
Question Posted:
Students also viewed these Organic Chemistry questions
-
Write an equation for each of the following reactions: a. 2-butene + HCl b. 3-hexene + HI c. 4-methylcyclopentene + HBr
-
Write an equation for each of the following reactions: a. Quinoline (page 395) + HCl b. Nitration of quinoline c. Quinoline + NaNH2 d. Quinoline + phenyllithium e. Quinoline + CH3I
-
Write an equation for each of the following. a. Burning of lithium metal in oxygen b. Burning of methylamine, CH3NH2, in excess oxygen (N ends up as N2) c. Burning of diethyl sulfide, (C2H5)2S, in...
-
How does MacKinnon analyze cases of sexual harassment where the woman complies with the sexual advance? She suggests that these cases are therefore not wrongful. She suggests that these cases are too...
-
An illumination of 180 lux on student desks and other work areas is the standard that architects use when designing lighting systems for schools. (a) If a ceiling is 2.50 m above a student work area,...
-
Peter S. Kastner, director of the consulting firm Vericours Inc., reported that 40% of all rebates are not redeemed because consumers either fail to apply for them or their applications are rejected....
-
For the balance sheet for Bethesda Imaging, shown in Table 2.6, identify three financial ratios that might be of interest to an investor in the company. What do the 5 -year trends for the ratios...
-
Check the fundamental theorem for gradients, using T = x2 + 4xy + 2yz3, the points a = (0, 0, 0), b = (1, 1, 1), and the three paths in Fig. 1.28:? (a) (0,0.0) ??? (1.0, 0) ??? (1, 1,0) ??? (1,...
-
Discuss how research can help the company meet those consumer trends. How do companies use evidence in management decisions (evidence-based management) to support strategic choices?
-
Morelli Electric Motor Corporation manufactures electric motors for commercial use. The company produces three models, designated as standard, deluxe, and heavy-duty. The company uses a job-order...
-
Draw the structure of a. A primary alkyl chloride, C4H9Cl. b. A tertiary alkyl bromide, C5H11Br. c. A secondary alkyl iodide, C6H11I.
-
Select an alkyl halide and a nucleophile that will give each of the following products: a. CH3OCH2CH2CH2CH3 b. HC¡CCH2CH2CH3 c. CH3CH2CH2NH2 d. CH3CH2CH2SCH2CH2CH3 e. f. CH2CN on OCH CH
-
Howard Rockness was worried. His company, Rockness Bottling, showed declining profits over the past several years despite an increase in revenues. With profits declining and revenues increasing,...
-
The Corner Grill needs a new refrigeration unit which costs $28,000. The unit has a 4-year life after which time it will be worthless. The unit belongs in a 20 percent CCA class. The equipment can be...
-
How much should investors pay for a 6%, semiannual coupon bond of Ford Motor Company? The bond has $1,000 par value and 19 years remaining to maturity. Investor's required return is 13%. The bond...
-
Amazon Inc. has semiannual coupon bonds with 5% coupon rate and 20 years remaining to maturity. The bonds are selling for 78% of par value. What is the (annual) yield of maturity of the bonds? Note...
-
(c) (10 pts) Suppose that the fund manager just shorted another portfolio worth of $10 million with a beta of 1.2, what position in the futures should the fund manager take now to make the combined...
-
A product earns an annual gross revenues of $90,000, the variable cost is $60. The fixed costs are $30,000 and the product is sell for $90. The quantity of product sold las year was 1,000. What is...
-
Roundhouse Tools has several potential warranty claims as a result of damaged tool kits. Review each situation and (1) determine the treatment for each situation as probable and estimable, probable...
-
Explain the term global capital markets. This chapter primarily discusses global equity markets. What other types of financial instruments are traded in these markets? How important are global...
-
a. Explain why the following reaction leads to the products shown: b. What product would be obtained from the following reaction? CH,CHCH,NH2 NaNO2 OH NH CH3C -CH, -NaNO CH CH, CH,
-
Describe how mescaline could be synthesized from benzene. The structure of mescaline is given on p. 622.
-
Propose a mechanism for the following reaction that explains why the configuration of the asymmetric carbon in the reactant is retained in the product: COO NaNO2 HCl NH2 COO
-
1. What traits do you admire in leaders and professionals from your own experience? Why? 2. Identify your leadership strengths and weaknesses. How do you plan to address the areas that need...
-
1. Define a project system. 2. List and discuss five major functions in project planning. 3. Describe the role of the project manager in project planning. 4. Develop a project planning model for the...
-
John and Frank are in an automobile accident. John sues Frank for $100,000.00 in a comparative negligence state. John has been assigned 40% of the fault by the jury and Frank 60% of the fault by the...
Study smarter with the SolutionInn App