Question: When the structure of compound A was determined in 1912, it was found to have an unusually long C-C bond and unusually large C-C-C bond

When the structure of compound A was determined in 1912, it was found to have an unusually long C-C bond and unusually large C-C-C bond angles, compared with the similar parameters for compound B (isobutane).

Explain why the indicated bond length and bond angle are larger for compound A.

1.611 A 1.535 A CH C(CH3)3 CH3 4C_C_C= 116" 4 C-C-C-110.80

Step by Step Solution

★★★★★

3.45 Rating (171 Votes )

There are 3 Steps involved in it

1 Expert Approved Answer

Step: 1 Unlock

Because severe van der Waals repulsions occur between the tert butyl groups in co... View full answer

Question Has Been Solved by an Expert!

Get step-by-step solutions from verified subject matter experts

Step: 2 Unlock

Step: 3 Unlock

Document Format (1 attachment)

902-C-O-O-S (91).docx

120 KBs Word File

Students Have Also Explored These Related Organic Chemistry Questions!

[The following information applies to the questions displayed below.] Taylor's is a popular restaurant that offers customers a large dining room and comfortable bar area. Taylor Henry, the owner and...

Compound A and compound B are both aromatic esters with molecular formula C 8 H 8 O 2 . When treated with bromine in the presence of iron tribromide, compound A is converted into only one product,...

When D-galactose was heated at 165C, a small amount of compound A was isolated: The structure of compound A was established, in part, by converting it to known compounds. Treatment of A with excess...

Compound A is an alkyne with molecular formula C 5 H 8 . When treated with aqueous sulfuric acid and mercuric sulfate, two different products with molecular formula C 5 H 10 O are obtained in equal...

Hello my friend please assist me with my discussion Interest Rates Negotiation is a soft skill that might just be one of the most important skills you will ever learn. For this Discussion you will...

NEED THIS ASAP PLEASE AND THANK YOU IN ADVANCE. HAVE A NICE DAY! The Battle for Value, 2004: FedEx Corp. vs. United Parcel Service, Inc. FedEx will produce superior financial returns for shareoners...

Evaluate the potential gains and losses for forwards,future,call options,put options and swaps. Outline and describe the different risks that each type of derivative contract faces. Describe...

Managing Scope Changes Case Study Scope changes on a project can occur regardless of how well the project is planned or executed. Scope changes can be the result of something that was omitted during...

Your end-of-semester assignment is as follows: (a) (i) read the two Economist articles entitled ?Debt is Good for You? (dated 01/25/2001) and ?Debtors? Prison? (dated 02/09/2009), which discuss the...

provide a brief summary of CSR-related marketing theory, and provide at least one way to expand the theory or make it better, and at least one way you will use it in the current format . 1.5 page 17...

12 Investing in Financially Distressed and Bankrupt Securities As we have learned from the history of the junk-bond market, investors have traditionally attached a stigma to the securities of...

An inventor claims to have developed a resistance heater that supplies 1.2 kWh of energy to a room for each kWh of electricity it consumes. Is this a reasonable claim, or has the inventor developed a...

The KC Television Ratings announced that their ratings are based on a sample of 1500 homes out of a population of entire homes. They claimed that their margin of error at 95% confidence level is 25%....

Evaluate the l i m i t , i f i t exists. ( I f a n answer does not exist, enter DNE. ) Hint: x + 5 i s a factor o f the numerator. lim x - 5 x 3 - 6 x + 9 5 x + 5

Conestoga Ltd. has the following estimated probability distribution of returns. Return Probability 4% ..............0.20 12 ..............0.50 14 ...............0.30 Calculate Conestogas expected...

Green Thumb Gardening is a small gardening service that uses activity-based costing to estimate costs for pricing and other purposes. The proprietor of the company believes that costs are driven...

The 2013 financial statements of Lexmark International, Inc., a leading developer, manufacturer, and sup-plier of printing, imaging, and device management, indicated that it reported an accounting...

The City of Sweetwater maintains an Employees' Retirement Fund, a single employer defined benefit plan that provides annuity and disability benefits. The fund is financed by actuarially determined...

A four-stock portfolio is made up as follows. Calculate the portfoliosbeta. Stock Current Value Beta $4,500 2,900 6,800 1,200 .8 .6 1.3 1.8

1. A researcher measures the heights of 40 university students who are the firstborn in their families and compares the 15 who come from large families to the 25 who come from smaller families.

Draw the three constitutional isomers that have the formula C 5 H 12 . TITI H-C-C-CC CC-H 11 1 II H H=C-H H H-C-C T 1 1 -C-C-H 2 | H-- H=C=C -CC-H 3

The formula C 4 H 10 O results in seven isomers. See how many you can draw.

Determine whether these structures represent the same compound or isomers; a) H-C. -C -C H-C-H H H b) H-C-C. H-C- H H H H-C-H H H TI C_CH C H H H c) H=C=C d) H-C-C H H-CH H-C- ...

REPLACEMENT ANALYSIS The Bigbee Bottling Company is contemplating the replacement of one of its bottling machines with a newer and more efficient one. The old machine has a book value of $625,000 and...

Mr. and Mrs. Tinker own a sizeable investment portfolio of stock in publicly held corporations. The couple has four childrenages 20, 22, 25, and 27with whom they want to share their wealth....

6. What would the Cash Flow of this project have to be in year 5 in order for the project to have an IRR of 10%? (show all your work) 4. Consider the cash flows below, the first of which occurs...