Which of the following K-value expressions, if any, is (are) rigorous? For those expressions that are not

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Which of the following K-value expressions, if any, is (are) rigorous? For those expressions that are not rigorous, cite the assumptions involved.
(a) Ki = ФiL/ФiV
(b) Ki = ФiL/ФiL
(c) Ki = ФiL
(d) Ki = γiL ФiL/ФiV
(e) Ki = Psi / P
(f) Ki = γiL ФiL/γiVФiV
(g) Ki = γiL Psi / P
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