Without looking at Table 24.2, rank the following compounds in order of ascending basicity. (a) p-Nitro aniline,

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Without looking at Table 24.2, rank the following compounds in order of ascending basicity.

(a) p-Nitro aniline, p-aminobenzaldehyde, p-Bromoaniline

(b) p-Chloroanilinc, p-aminoacetophenone, p-methyl aniline

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Question Posted: Mar 08, 2011 04:38 AM

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Without looking at Table 24.2, rank the following compounds in order of ascending basicity. (a) p-Nitro aniline,

Question:

Table 24.2 Base Strength of Some p-Substituted Anilines -NH2 + H20 NH3 "OH Substituent, Y pKa -NH2 Stronger base 6.15 5.34 Activating groups -OCH3 -CH3 5.08 4.63 3.98 -Ci -Br 3.86 Deactivating groups -CN 1.74 Weaker -NO2 1.00 base

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The basicity order of substituted arylamines is the same as their react...View the full answer

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