Question: A reluctant first-order substrate can be forced to ionize by adding some silver nitrate (one of the few soluble silver salts) to the reaction. Silver

A reluctant first-order substrate can be forced to ionize by adding some silver nitrate (one of the few soluble silver salts) to the reaction. Silver ion reacts with the halogen to form a silver halide (a highly exothermic reaction), generating the cation of the alkyl group.

Give mechanisms for the following silver-promoted rearrangements.
(a)

A reluctant first-order substrate can be forced to ionize by

(b)

CHi CH3 AgNO3. H2O CHC-CH-CH CH2l AgNO3, H2O/CH,CH2OH

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