Basing your answers on the bond dissociation energies in Table 4.3, calculate which of the following reactions
Question:
(a) (CH3)2CHOH + HF -†’ (CH3)2CHF + H2O
(b) (CH3)2CHOH + HCl -†’ (CH3)2CHCl + H2O
(c) CH3CH2CH3 + HCl -†’ (CH3)2CHCl + H2
Transcribed Image Text:
Bond Dissociation Energies of Some Representative Compounds* TABLE 4.3 Bond dissociation energy Bond dissociation energy Bond kJ/mol (kcal/mol) Bond kJ/mol (kcal/mol) Diatomic molecules 435 159 242 192 150 (104) (38) (58) (46) (36) 568 431 366 297 (136) (103) Cl-CI (71) Alkanes (104) (98) (98) (95) (98) (91) 368 355 (88) (85) CH3-H CH3CH2-H CH3CH2CH2-H (CH3)2CH-H (CH3)2CHCH2H 410 (CH3)3C-H 435 CH3 CH3 CH3CHz-CH3 397 (84) (CH3)2CH-CH3 351 (CH3)3C-CH3 380 334 Alkyl halides (108) (CH3)2CH-IF CH3-F CHa-CI CH3 Br CH3l CH3CH2Cl CH3CH2CH2-Cl 349 293 234 338 343 (83.5) (CH3)2CH-CI (70) (56) (81) (82) 439 339 284 330 263 (105) (81) (68) (79) (63) (CH3)2CH-Br (CH3)3C-cI (CH3)3C-Br Water and alcohols HO-H CH2O-H CH3 OH 497 426 380 (102) (91) CH3CH2_OH (CH3)2CH-OH (CH3)3C-OH 380 385 380 (91) (92)
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