Question: Consider the extraction of Mn+ from aqueous solution into organic solution by reaction with protonated ligand, HL: Rewrite Equation 22-13 in terms of Kextraction and

Consider the extraction of Mn+ from aqueous solution into organic solution by reaction with protonated ligand, HL:

M

Rewrite Equation 22-13 in terms of Kextraction and express Kextraction in terms of the constants in Equation 22-13. Give a physical reason why each constant increases or decreases Kextraction.


Equation 22-13

M"*(aq) + nHL(org) = ML(org) + nH*(aq) [MLJorg[H* Tag [M"+ laq[HL]org Kextraction=

M"*(aq) + nHL(org) = ML(org) + nH*(aq) [MLJorg[H* Tag [M"+ laq[HL]org Kextraction=

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