Question: Constant-boiling aqueous HCl can be used as a primary standard for acid-base titrations. When ~20 wt% HCl (FM 36.461) is distilled, the composition of the

Constant-boiling aqueous HCl can be used as a primary standard for acid-base titrations. When ~20 wt% HCl (FM 36.461) is distilled, the composition of the distillate varies in a regular manner with the barometric pressure:

(a) Make a graph of the data in the table to find the weight percent of HCl collected at 746 Torr.
(b) What mass of distillate (weighed in air, using weights whose density is 8.0 g/mL) should be dissolved in 1.000 0 L to give 0.100 00 M HCl? The density of distillate over the whole range in the table is close to 1.096 g/mL. You will need this density to change the mass measured in vacuum to mass measured in air. See Section 2-3 for buoyancy corrections.

P (Torr) 770 760 750 740 730 HCl (/100 g solution) 20.196 20.220 20.244 20.268 20.292

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