Question: For methyl chloride at 100(C the second and third virial coefficients are: Calculate the work of mechanically reversible, isothermal compression of 1 mol of methyl

For methyl chloride at 100(C the second and third virial coefficients are:

Calculate the work of mechanically reversible, isothermal compression of 1 mol of methyl chloride from 1 bar to 55 bar at 100(C. Base calculations on the following forms of the virial equation:
(a)

(b)Z = 1 + B( P + C( P2
Where

Why don't both equations give exactly the same result?

B-242.5 cm moI C 25.200 cm" mol-2 B C

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