Mercury has several stable isotopes, among them 198 Hg and 202 Hg. The strong spectral line of

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Mercury has several stable isotopes, among them 198Hg and 202Hg. The strong spectral line of mercury at about 546.07 nm is a composite of spectral lines from the various mercury isotopes. The wavelengths of this line for 198Hg and 202Hg are 546.07532 and 546.07355 nm, respectively. What must be the resolving power of a grating capable of resolving these two isotopic lines in the third-order spectrum? If the grating is illuminated over a 2-cm-wide region, what must be the number of lines per centimeter of the grating?

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