Question: Predict the form of the cross-peak multiplet that would be seen in a COSY spectrum of an I2S and of an I$S spin system, assuming
Predict the form of the cross-peak multiplet that would be seen in a COSY spectrum of an I2S and of an I$S spin system, assuming that the I and S spins are affected by both 90° pulses. [The calculation is simplest if you start with 1z as the equilibrium magnetization, but you should also attempt it starting from z. When predicting the form of the multiplets use the graphical approach illustrated in Fig. 8.10 on page 194.J
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We will begin by calculating the form of the COSY spectrum of the I 2 S spin system Starting with I 1z the first 90 pulse generates I 1y This term then evolves under the offset of I 1 and the coupling ... View full answer
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