Show that if one expands U(R) in Fig. 4.6 in a Taylor series about R = Re

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Show that if one expands U(R) in Fig. 4.6 in a Taylor series about R = Re and neglects terms containing (R - Re)3 and higher powers (these terms are small for R near Re), then one obtains a harmonic-oscillator potential with k = d2/dR2| R = Re.

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Quantum Chemistry

ISBN: 978-0321803450

7th edition

Authors: Ira N. Levine

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Question Posted: May 26, 2016 06:18 AM

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Show that if one expands U(R) in Fig. 4.6 in a Taylor series about R = Re

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The Taylor series 485 of Prob 41 with x R fx UR and a R e gives UR UR e 0 UR e RR e ...View the full answer

Quantum Chemistry

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