Shown here are some pKa data for simple dibasic acids. How can you account for the fact

Question:

Shown here are some pKa data for simple dibasic acids. How can you account for the fact that the difference between the first and second ionization constants decreases with increasing distance between the carboxyl groups?

Fantastic news! We've Found the answer you've been seeking!

Step by Step Answer:

Related Book For book-img-for-question

Organic Chemistry

ISBN: 9780495112587

7 Edition

Authors: John McMurry

See More Books

Question Posted: Feb 23, 2011 06:26 AM

See More Questions

How can you account for the fact that 2, 2, 6-trimethylcyclohexanone yields no detectable aldol product even though it has an acidic hydrogen?
How can you account for the fact that cis-1, 3-pentadicne is much less reactive than trans-1, 3-pentadiene in the DielsAlder reaction?
How can you account for the fact that normal rain is slightly acidic?
The following data applies to the two unrelated companies Lloyd Ltd and Cole Ltd: All taxable and deductible temporary differences relate to the profit or loss. Assume a corporate tax rate of 30%. A....
1. To what degree do you agree or disagree with the B-Team's goal for world governments to reach net zero CO2 or greenhouse gas (GHG) emissions by 2050? 2. Should governments of developing economies...
A vertical cylinder 6 ft tall and 1 ft in diameter might be used to approximate a man for heat-transfer purposes. Suppose the surface temperature of the cylinder is 78F, h = 2 Btu/h ft2 F, the...
The industry standard for balanced voltages in three phase systems is 2%. When the output data is taken on a VFD, the voltages are not easily read. What should be the current imbalance based on a...
B-You is a consulting firm that works with managers to improve their interpersonal skills. Recently, a representative of a high-tech research firm approached B-Yous owner with an offer to contract...
Outline the constitutional amendments that form the basis of the criminal justice system and explain the right afforded to the individual by that amendment. 2. Explain the US Supreme Court's role in...
Excess capacity Krogh Lumbers 2005 financial statements are shown here. a. Assume that the company was operating at full capacity in 2005 with regard to all items except fixed assets; fixed assets in...
In humans, the final product of purine degradation from DNA is uric acid, pKa = 5.61, which is excreted in the urine. What is the percent dissociation of uric acid in urine at a typical pH = 6.0? Why...
Predict the product of the reaction of p-methyl benzoic acid with each of the following: (a) LiAlH 4 , then H 3 O + (b) N-Bromosuccinimide in CCl 4 (c) CH 3 MgBr in ether, then H 3 O + (d) KMnO 4 , H...
Discuss the costs associated with investing in ETFs.
Locate an HR professional who is willing to be interviewed for about 15 minutes. You can do this by visiting an organization, attending a meeting or conference where there are likely to be HR...
Calculate the life insurance gross premium for an insurance company, XYZ Life, under the following assumptions. Please round your answer to the nearest cent. 1-year term insurance for a 30-year-old...
In Co-operators General Insurance Company v. Kane, 2017 BCSC 1720, Kane was sued for "unintentional battery assault". Could you help us to understand the meaning of unintentional battery assault?
Can you identify, describe, and explain the issue and provide any historical information about diversion programs?
"Supreme Court backs binding arbitration agreements By Michelle Singletary If you look carefully and you probably haven't at the fine print in your credit card agreement or in many of the consumer...
Prove Proposition 8.18. Proposition 8.18 In the context of the model described above (see Harrison & Kreps [903]), a price process (P)EN is consistent if and only if it satisfies the following...
The nitrogen atoms in N2 participate in multiple bonding, whereas those in hydrazine, N2H4, do not. (a) Draw Lewis structures for both molecules. (b) What is the hybridization of the nitrogen atoms...
What are the name and formula of the compound commonly used in the manufacture of glass to increase the index of refraction?
Treating oxytocin with certain reducing agents (e.g., sodium in liquid ammonia) brings about a single chemical change that can be reversed by air oxidation. What chemical changes are involved?
What classes of reactions are involved in the cleavage of the Fmoc group with piperidine, leading to the unprotected amino acid and the fluorene by-product? Write mechanisms for these reactions.
Show all steps in the synthesis of GVA using the tert-butyloxycarbonyl (Boc) group as a protecting group.
Let R denote the region in the xy-plane that lies in the first quadrant and is bounded by the lines y = 1 - x, y = 2 - x, y = x + 1, and y = x - 1. Set u=x+y and v = y-x. (a) Solve for x and y in...
Reply to The culture established by Mr. Kelleher places importance on employee happiness, which directly influences customer satisfaction and overall organizational achievements. To maintain this...
First, technology has a major impact on talent shortage. With the increased use of AI, there are fewer data analysis jobs required, so technology can potentially replace some forms of supply chain...

Shown here are some pKa data for simple dibasic acids. How can you account for the fact

Question:

Name Structure pk, pK2 Oxalic Succinic 4.2 1.2 HO,cco,H но -ссн-сн,со,н но -СICH2),cо,H 4.2 5.6 4.4 Adipic 5.4

Step by Step Answer:

Inductive effects of functional groups are transmitted through bonds For oxalic acid the e...View the full answer

Organic Chemistry

Students also viewed these Organic Chemistry questions