a. Derive Eq. 7.4-8. b. Derive Eq. 7.4-12. c. Obtain an expression for the fugacity of a
Question:
a. Derive Eq. 7.4-8.
b. Derive Eq. 7.4-12.
c. Obtain an expression for the fugacity of a pure species that obeys the van der Waals equation of state in terms of Z, B = P b/RT, and A = aP/(RT)2 (i.e., derive Eq. 7.4-13).
Waals equation.
d. Repeat the derivation with the Peng-Robinson equation of state (i.e., derive Eq. 7.4-14a).
Transcribed Image Text:
In fv (T, P) P V=ZV RT/P (RT AT SK (HT - P) - PdV-In ZV + (ZV - 1) (7.4-8)
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Related Book For
Chemical Biochemical And Engineering Thermodynamics
ISBN: 9780470504796
5th Edition
Authors: Stanley I. Sandler
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