Question: Many ionic compounds are considered to pack in such as way that the anions form a close-packed lattice in which the metal cations fill holes
Many ionic compounds are considered to pack in such as way that the anions form a close-packed lattice in which the metal cations fill holes or interstitial sites left between the anions. These lattices, however, may not necessarily be as tightly packed as the label “close-packed” implies. The radius of an F– ion is approximately 133 pm. The edge distances of the cubic unit cells of LiF, NaF, KF, RbF, and CsF, all of which pack in the rock-salt structure, are 568 pm, 652 pm, 754 pm, 796 pm, and 850 pm, respectively. Which of these lattices, if any, can be thought to be based on close-packed arrays of F– ions treated as hard spheres? Justify your conclusions.
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To determine if the lattices of LiF NaF KF RbF and CsF can be considered as closepacked arrays of F ... View full answer
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