Question: Many ionic compounds are considered to pack in such as way that the anions form a close-packed lattice in which the metal cations fill holes

Many ionic compounds are considered to pack in such as way that the anions form a close-packed lattice in which the metal cations fill holes or interstitial sites left between the anions. These lattices, however, may not necessarily be as tightly packed as the label “close-packed” implies. The radius of an F ion is approximately 133 pm. The edge distances of the cubic unit cells of LiF, NaF, KF, RbF, and CsF, all of which pack in the rock-salt structure, are 568 pm, 652 pm, 754 pm, 796 pm, and 850 pm, respectively. Which of these lattices, if any, can be thought to be based on close-packed arrays of F ions treated as hard spheres? Justify your conclusions.

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