In the determination of lead in a paint sample, it is known that the sampling variance is

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In the determination of lead in a paint sample, it is known that the sampling variance is 10 ppm while the measurement variance is 4 ppm. Two different sampling schemes are under consideration:
Scheme a: Take five sample increments and blend them. Perform a duplicate analysis of the blended sample.
Scheme b: Take three sample increments, and perform a duplicate analysis on each.
Which sampling scheme, if any, should have the lower variance of the mean?

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Fundamentals Of Analytical Chemistry

ISBN: 9780357450390

10th Edition

Authors: Douglas A. Skoog, Donald M. West, F. James Holler, Stanley R. Crouch

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