Describe a hybridization scheme for the central Cl atom in the molecule ClF 3 that is consistent
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Describe a hybridization scheme for the central Cl atom in the molecule ClF3 that is consistent with the geometric shape pictured in Table 10.1. Which orbitals of the Cl atom are involved in overlaps, and which are occupied by lone-pair electrons?
Table 10.1
Transcribed Image Text:
TABLE 10.1 Molecular Geometry as a Function of Electron-Group Geometry Number of Electron Groups 2 3 4 5 6 Electron- Group Geometry linear trigonal planar trigonal planar tetrahedral tetrahedral tetrahedral trigonal bipyramidal trigonal bipyramidal trigonal bipyramidal trigonal bipyramidal octahedral octahedral octahedral Number of Lone Pairs 0 0 1 1 2 0 AX4 1 2 3 Molecular VSEPR Notation Geometry 0 AX₂ AX3 0 AX5 2 AX₂E AX₂E AX₂E₂ AX₂Eb AX₂E2 AX₂E3 AX6 1 AX-E AX4E2 (linear) X (trigonal planar) X X (bent) (tetrahedral) .. X (trigonal pyramidal) (bent) X X (seesaw) X X (trigonal bipyramidal) X (linear) (T-shaped) X X +4+ (octahedral) X X (square pyramidal) (square planar) Ideal Bond Angles Example 180⁰ 120⁰ 120⁰ 109.5⁰ 109.5⁰ 109.5⁰ NH3 90° 180° BeCl₂ 90° BF3 90⁰, 120° PC15 90° SO₂ 90⁰, 120° SF4 90° CH4 OH₂ CIF₁ XeF₂ SF6 BrF5 XeF4 Carey B. Van Loon Carey B. Van Loon Carey B. Van Loon Carey B. Van Loon Carey B. Van Loon
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Fig ClF3 Explanation When we talk about the hybridization of chlorine trifluoride we have to conside...View the full answer
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Related Book For
General Chemistry Principles And Modern Applications
ISBN: 9780132931281
11th Edition
Authors: Ralph Petrucci, Jeffry Madura, F. Herring, Carey Bissonnette
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