In a fused magma liquid from which silicate minerals crystallize, the metal ions can be four-coordinate. In

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In a fused magma liquid from which silicate minerals crystallize, the metal ions can be four-coordinate. In olivine crystals, the M(II) co-ordination sites are octahedral. Partition coefficients, which are defined as Kp = [M(II)]olivine/[M(II)]melt, follow the order Ni(II) > Co(II) > Fe(II) > Mn(II). Account for this in terms of ligand-field theory. (See I.M. Dale and P. Henderson, 24th Int. Geol. Congress, Sect. 10, 1972, 105.)

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Inorganic Chemistry

ISBN: 9780198768128

7th Edition

Authors: Mark Weller, Tina Overton, Jonathan Rourke

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