In their paper Recent discoveries of polyhalogen anions from bromine to fluorine (Z. Anorg. Allg. Chem., 2014,
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In their paper ‘Recent discoveries of polyhalogen anions— from bromine to fluorine’ (Z. Anorg. Allg. Chem., 2014, 640, 7, 1281), H. Haller and S. Riedel described the synthesis and structure elucidation of several new polyhalide ions.
(a) Outline the synthetic strategies that enabled these polyhalide ions to be synthesized.
(b) Sketch the structures of the Br5+, Br133−, and Cl7− ions.
(c) Referring to earlier work on polyiodides, discuss how I3− units coordinate to build up polyiodides.
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a Synthetic Strategies for Polyhalide Ions In their paper Haller and Riedel likely employed a variety of synthetic strategies to prepare polyhalide ions Some common synthetic strategies for preparing ...View the full answer
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Related Book For 
Inorganic Chemistry
ISBN: 9780198768128
7th Edition
Authors: Mark Weller, Tina Overton, Jonathan Rourke
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