Na[W( 5 -C 5 H 5 )(CO) 3 ] reacts with 3-chloroprop-1-ene to give a solid, A,

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Na[W(η5-C5H5)(CO)3] reacts with 3-chloroprop-1-ene to give a solid, A, which has the molecular formula [W(C3H5) (C5H5)(CO)3]. Compound A loses carbon monoxide on exposure to light and forms compound B, which has the formula [W(C3H5) (C5H5)(CO)2]. Treating compound A with hydrogen chloride and then potassium hexafluoridophosphate, K+PF6, results in the formation of a salt, C, which has the molecular formula [W(C3H6) (C5H5)(CO)3]PF6. Use this information and the 18-electron rule to identify the compounds A, B, and C. Sketch a structure for each, paying particular attention to the hapticity of the hydrocarbons.

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Inorganic Chemistry

ISBN: 9780198768128

7th Edition

Authors: Mark Weller, Tina Overton, Jonathan Rourke

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