Compute the standard heat of reaction for each of the following reactions taking place at 298.15 K

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Compute the standard heat of reaction for each of the following reactions taking place at 298.15 K in dilute aqueous solution at zero ionic strength.
(a) D-Glucose + ATP2 → D-Glucose 6-phosphate + ADP−

(b) D-Glucose 6-phosphate → D-Fructose 6-phosphate

(c) D-Fructose 6-phosphate + ATP2 → D-Fructose 1,6-biphosphate2− + ADP−

(d) D-Glucose + 2 ADP− + 2H2 PO4 + 2 NAD+ → 2 Pyruvate−+ 2 ATP2 + 2 NADH + 4H+ + 2H2O

(e) D-Glucose + 2 ADP− + 2H2 PO4 → 2 Lactate + 2 ATP2+ 2H+ + 2H2O

(f) D-Glucose + 2 ADP− + 2H2 PO4 → 2CO2 + 2 Ethanol + 2 ATP2− + 2H2O

(g) 2 NADH + O2 + 2H+ → 2 NAD+ + 2H2O

(h) ADP− + H2 PO4 →ATP2 + H2O

(i) 2 NADH + 2 ADP− + 2HPO4 + O2 + 2H+ → 2 NAD+ + 2 ATP2− + 4H2O

(j) D-Fructose + 2 ADP− + 2H2 PO → 2CO2 + 2 Ethanol +2 ATP2− + 2H2O

(k) D-Galactose + 2 ADP− + 2H2 PO → 2CO2 + 2

(l) Ethanol + 2 ATP2 + 2H2O NH+4 + L-aspartate− + ATP2− → L-asparagine + ADP− + H2 PO4

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Introduction To Chemical Engineering Thermodynamics

ISBN: 9781259696527

8th Edition

Authors: J.M. Smith, Hendrick Van Ness, Michael Abbott, Mark Swihart

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