The following empirical two-parameter expression has been proposed for correlation of excess properties of symmetrical liquid mixtures:

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The following empirical two-parameter expression has been proposed for correlation of excess properties of symmetrical liquid mixtures:
Here, quantities A and B are parameters that depend at most on T.
(a) Determine from the given equation the implied expressions for M̅E1 and M̅E2 .
(b) Show that the results of part (a) satisfy all necessary constraints for partial excess properties.
(c) Determine from the results of part (a) expressions for (M̅E1)∞ and (M̅E2)∞.

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Introduction To Chemical Engineering Thermodynamics

ISBN: 9781259696527

8th Edition

Authors: J.M. Smith, Hendrick Van Ness, Michael Abbott, Mark Swihart

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