Wilson's parameters for the chloroform-methanol system at (35^{circ} mathrm{C}) are given by (lambda_{12}-lambda_{11}=-1.522 mathrm{~kJ} / mathrm{mol}-mathrm{K}) and
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Wilson's parameters for the chloroform-methanol system at \(35^{\circ} \mathrm{C}\) are given by \(\lambda_{12}-\lambda_{11}=-1.522 \mathrm{~kJ} / \mathrm{mol}-\mathrm{K}\) and \(\lambda_{12}-\lambda_{22}=7.559 \mathrm{~kJ} / \mathrm{mol}-\mathrm{K}\). Estimate the VLE data for the system at \(35^{\circ} \mathrm{C}\) if \(V_{1}^{l}=80.67 \times 10^{-6} \mathrm{~m}^{3} / \mathrm{mol}\) and \(V_{2}^{l}=40.73 \times 10^{-6} \mathrm{~m}^{3} / \mathrm{mol}\).
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