Work Prob. 13.49 for the NRTL equation. Prob. 13.49 For one of the binary systems listed in

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Work Prob. 13.49 for the NRTL equation.

Prob. 13.49

For one of the binary systems listed in Table 13.10, based on Eq. (13.19) and the Wilson equation, make the following calculations:
(a) BUBL T : P = 101.33 kPa, x1 = 0.3.
(b) DEW T : P = 101.33 kPa, y1 = 0.3.
(c) P, T − flash: P = 101.33 kPa, T = ½ (Tbubble + Tdew), z1 = 0.3.
(d) If an azeotrope exists at P =101.33 kPa, find Taz and xaz1 = yaz1.

Problems 13.43 through 13.54 require parameter values for the Wilson or NRTL equation for liquid-phase activity coefficients. Table 13.10 gives parameter values for both equations. Antoine equations for vapor pressure are given in Table B.2, Appendix B.

Table 13.10

Table B.2, Appendix B.

 Eq. (13.19)

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Introduction To Chemical Engineering Thermodynamics

ISBN: 9781259696527

8th Edition

Authors: J.M. Smith, Hendrick Van Ness, Michael Abbott, Mark Swihart

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