a. Show by substitution into Equation (15.19) that the eigenfunctions of HË for a box with lengths

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a. Show by substitution into Equation (15.19) that the eigenfunctions of Hˆ for a box with lengths along the x, y, and z directions of a, b, and c, respectively, are 

п.лz И,лу sin sin = N sin nn,n (x.y,z) %3D

b. Obtain an expression for Enx, ny, nz in terms of nx, ny, nz, and a, b, and c.

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Physical Chemistry

ISBN: 978-0321812001

3rd edition

Authors: Thomas Engel, Philip Reid

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