Fill in the missing step in the derivation that led to the calculation of the spectral line

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Fill in the missing step in the derivation that led to the calculation of the spectral line shape in Figure 19.24. Starting from

НЕ -Е -w Ez – E – lv НЕ, -Е, +i 21 Eo| 1-eй 2 а(0) %3 д 1-e E2 – E + hv

and neglecting the first term in the parentheses, show that

оiОда, ) — Е Ги7sin'(E, - E - i)2H] (E, – E, – hv)?

Figure 19.24

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Physical Chemistry

ISBN: 978-0321812001

3rd edition

Authors: Thomas Engel, Philip Reid

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