In Problem P19.29 you obtained the result J max = ½ 4I k B T/h 2 1]

In Problem P19.29 you obtained the result

J _max = ½ ˆš4I k_BT/h² €“ 1]

Using this result, estimate T for the simulated ¹H³⁵Cl rotational spectra shown in the following figure. Give realistic estimates of the precision with which you can determine T from the spectra. In generating the simulation, we assumed that the intensity of the individual peaks is solely determined by the population in the originating state and that it does not depend on the initial and final J values. 

Transcribed Image Text:

2800 2900 3000 3100 3200 Frequency/(cm-1) Intensity 2800 2900 3000 3100 3200 Frequency/(cm-1) Intensity