In Problem P19.29 you obtained the resultJ max = ½

In Problem P19.29 you obtained the result

J max = ½ √4I kBT/h2 – 1]

Using this result, estimate T for the simulated 1H35Cl rotational spectra shown in the following figure. Give realistic estimates of the precision with which you can determine T from the spectra. In generating the simulation, we assumed that the intensity of the individual peaks is solely determined by the population in the originating state and that it does not depend on the initial and final J values. 

2800 2900 3000 3100 3200 Frequency/(cm-1) Intensity


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