The Joule coefficient is defined by (T /V) U = (1/C V )[P T(P/T) V ].

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The Joule coefficient is defined by (∂T /∂V)U = (1/CV )[P − T(∂P/∂T)V ]. Calculate the Joule coefficient for an ideal gas and for a van der Waals gas.

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Physical Chemistry

ISBN: 978-0321812001

3rd edition

Authors: Thomas Engel, Philip Reid

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