The rotational terms of a symmetric top, allowing for centrifugal distortion, are commonly written (a) Develop an

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The rotational terms of a symmetric top, allowing for centrifugal distortion, are commonly written

(a) Develop an expression for the wavenumbers of the allowed rotational transitions.

(b) The following transition frequencies (in gigahertz, GHz) were observed for CH₃F:

Determine the values of as many constants in the expression for the rotational terms as these values permit.

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Physical Chemistry Thermodynamics And Kinetics

ISBN: 9781464124518

10th Edition

Authors: Peter Atkins, Julio De Paula

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Question Posted: Oct 20, 2022 02:37 AM

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The rotational terms of a symmetric top, allowing for centrifugal distortion, are commonly written (a) Develop an

Question:

F(J,K)=BJ(J+1)+(Ã-B)K² -Ď₁J² (J+1)²-ĎJKJ(J+1)K²-ĎKK4

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a The wavenumbers of the allowed rotational transitions can be expressed as v J J w...View the full answer

Physical Chemistry Thermodynamics And Kinetics

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