Thorn et al. (J. Phys. Chem. 100, 14178 (1996)) carried out a study of Cl 2 O(g)

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Thorn et al. (J. Phys. Chem. 100, 14178 (1996)) carried out a study of Cl2O(g) by photoelectron ionization. From their measurements, they report ΔfH(Cl2O)=+77.2 kJmol−1. They combined this measurement with literature data on the reaction Cl2O (g)+H2O(g)→2 HOCl(g), for which K=8.2×10−2 and ΔrS =+16.38 JK−1mol−1, and with readily available thermodynamic data on water vapour to report a value for ΔfH(HOCl). Calculate that value. All quantities refer to 298K.

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