When benzophenone is illuminated with ultraviolet light it is excited into a singlet state. This singlet changes

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When benzophenone is illuminated with ultraviolet light it is excited into a singlet state. This singlet changes rapidly into a triplet, which phosphoresces. Triethylamine acts as a quencher for the triplet. In an experiment in methanol as solvent, the phosphorescence intensity varied with amine concentration as shown below. A time-resolved laser spectroscopy experiment had also shown that the half-life of the fluorescence in the absence of quencher is 29 µs. What is the value of kq?

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Physical Chemistry

ISBN: 9780716787594

8th Edition

Authors: Peter Atkins, Julio De Paula

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