a. Use Troutons rule, Hvap (88 J mol-1 K-1) H vap (88 J mol -1

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a. Use Trouton’s rule, ΔHvap° ≈ (88 J mol-1 K-1) ΔH°vap ≈ (88 J mol-1 K-1) to estimate the enthalpy of vaporization of octane (b.p. 126°C). (b.p. 126°C)
b. Use the form of the Clausius-Clapeyron equation below to estimate the vapor pressure in bar of octane at the column temperature in Figure 24-9 (70°C).(70°C).

c. Calculate the vapor pressure in bar for hexane (b.p. 69°C)(b.p. 69°C) at 70°C.70°C.
d. What is the relationship between solute vapor pressure and retention?
e. Why is the technique called “gas chromatography” if retained analytes are only partially vaporized?

Figure 24-9

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Quantitative Chemical Analysis

ISBN: 9781319164300

10th Edition

Authors: Daniel C. Harris, Charles A. Lucy

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