Question: 1. The following initial rate data are for the ozonization of pentene in carbon tetrachloride solution at 25 o C : C 5 H 10

1.

The following initial rate data are for the ozonization of pentene in carbon tetrachloride solution at 25 oC: C5H10 + O3 C5H10O3

Experiment [C5H10]o, M [O3]o, M Initial Rate, Ms-1
1 7.9210-2 1.7410-2 137
2 7.9210-2 3.4810-2 273
3 0.158 1.7410-2 272
4 0.158 3.4810-2 545

Complete the rate law for this reaction in the box below. Use the form k[A]m[B]n , where '1' is understood for m or n and concentrations taken to the zero power do not appear. Don't enter 1 for m or n

Rate =

From these data, the rate constant is M-1s-1.

2. The following initial rate data are for the reaction of UO2+ with hydrogen ion in aqueous solution: 2 UO2+ + 4 H+U4+ + UO22+ + 2 H2O

Experiment [UO2+]o, M [H+]o, M Initial Rate, M s-1
1 1.0810-3 0.102 1.7410-5
2 2.1610-3 0.102 6.9510-5
3 1.0810-3 0.204 3.4710-5
4 2.1610-3 0.204 1.3910-4

Complete the rate law for this reaction in the box below. Use the form k[A]m[B]n , where '1' is understood for m or n and concentrations taken to the zero power do not appear. Don't enter 1 for m or n.

Rate =

From these data, the rate constant is M-2s-1.

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