1. Using data in Appendix C, calculate AH, AS', and AG at 298K for each of...

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1. Using data in Appendix C, calculate AH, AS', and AG at 298K for each of the following reactions. Indicate whether the reaction is spontaneous at 298K under standard conditions. (a) Ti (s) + 2 Cl₂(g) → TiCl4 (1) (b) HCI (aq) + NaOH (aq) → NaCl (aq) + H₂O (1) (c) CF4 (g) + 2 H₂ (g) → C(s) + 4 HF (g) (d) Na₂CO3 (s) + 2 HNO3(aq) → 2 NaNO3(aq) + CO₂ (g) + H₂O (1) THERMODYNAMIC QUANTITIES FOR SELECTED SUBSTANCES AT 298.15 K (25 °C) Substance Aluminum Al(s) AICI3(s) Al₂O3(s) Barium Ba(s) BaCO3(s) BaO(s) Beryllium Be(s) BeO(s) Be (OH)2 (s) Bromine Br(g) Br (aq) Br₂(8) Br₂(1) HBr(g) Calcium Ca(g) Ca(s) CaCO3(s, calcite) CaCl₂(s) CaF₂(s) CaO(s) Ca(OH)2(s) CaSO4(s) Carbon C(g) C(s, diamond) C(s, graphite) CC14(8) CC1₂ (1) CF4(8) CH₂(8) AH; (kj/mol) 0 -705.6 -1669.8 0 -1216.3 -553.5 0 -608.4 -905.8 111.8 - 120.9 30.71 -36.23 179.3 0 -1207.1 -795.8 -1219.6 -635.5 -986.2 -1434.0 9718.4 1.88 0 -106.7 -139.3 -679.9 -74.8 AG; (kj/mol) 0 -630.0 -1576.5 0 - 1137.6 -525.1 0 -579.1 -817.9 82.38 - 102.8 3.14 0 -53.22 145.5 0 -1128.76 -748.1 -1167.3 -604.17 -898.5 -1321.8 672.9 2.84 0 -64.0 -68.6 -635.1 -50.8 S (j/mol-K) 28.32 109.3 51.00 63.2 112.1 70.42 9.44 13.77 50.21 174.9 80.71 6H 245.3 152.3 198.49 154.8 41.4 92.88 104.6 68.87 39.75 83.4 106.7 158.0 309.4 214.4 262.3 186.3 2.43 5.69 Will Substance C₂H₂(8) C₂H4(8) C₂H6(8) C3H8(8) C4H10(8) C4H10(1) C6H6(8) C6H6(1) CH₂OH(g) CH₂OH(1) C₂H5OH (8) C₂H₂OH(1) C6H12O6(S) CO(g) CO₂(8) CH3COOH(1) Cesium08 Cs(g) Cs(1) Cs(s) ELLIPS CsCl(s) Chlorine CI(g) HW CI (aq) Cl₂(8) 11.8 HCl(aq) HCI(g) Chromium Cr(g) Cr(s) E Cr₂O3(s) Cobalt Co(g) Co(s) B AH; (kj/mol) 226.77 52.30 -84.68 -103.85 -124.73 -147.6 82.9 49.0 -201.2 -238.6 al-235.1 -277.7 -1273.02 -110.5 06-393.5 -487.0 76.50 2.09 1200 -442.8 121.7 SHOO 1-167.2 -92.30 397.5 22000 -1139.7 APPENDIX C 439 0 AG; (kj/mol) 209.2 68.11 -32.89 -23.47 -15.71 -15.0 129.7 124.5 -161.9 -166.23 08-168.5 1-174.76 25-910.4 -137.2 40-394.4 -392.4 8-167.2-131.2 49.53 08 0.03 eat200 -414.4 105.7 150 2-131.2 -95.27 D 352.6 LABO -1058.1 EXIDE 393 0 S' (j/mol-K) 200.8 219.4 229.5 269.9 310.0 231.0 269.2 172.8 237.6 126.8 282.7 160.7 212.1 197.9 213.6 159.8 175.6 92.07 85.15 101.2 165.2 56.5 222.96 56.5 186.69 174.2 23.6 81.2 179 28.4 121 1214 APPENDIX C Thermodynamic Quantities for Selected Substances at 298.15 K (25 °C) Substance Copper Cu(g) Cu(s) CuCl₂(s) CuO(s) Cu₂O(s) Fluorine F(g) F (aq) F₂(8) HF(g) Hydrogen H(g) H*(aq) H*(8) H₂(8) ES lodine 051 I(g) 58 (8) 00 12(8) LESS 1₂(s) e HI(g) E Iron Fe(g) Fe(s) 21 Fe²+ (aq) Fe³+ (aq) FeCl₂(s) FeCl3(s) FeO(s) zal Fe₂O3(s) Fe3O4(s) FeS₂(s) Lead Pb(s) PbBr₂(S) PbCO3(s) 2 Pb(NO3)2(aq) Pb(NO3)2(S) PbO(s) Lithium Li(g) Li(s) AH; (kj/mol) 338.4 0 -205.9 -156.1 -170.7 80.0 -332.6 0 -268.61 217.94 0 1536.2 0 28106.60 8-55.19 A0162.25 STEL O 25.94 415.5 EERO 20.0-87.86 (-47.69 -341.8 -400 -271.9 -822.16 -1117.1 1-171.5 0 -277.4 -699.1 -421.3 -451.9 -217.3 159.3 0 (fo AG; PROSPERT (kj/mol) (i/mol-K) 298.6 0 -161.7 -128.3 -147.9 61.9 -278.8 0 88-270.70 203.26 0 1517.0 8.1000 Le 70.16 1.-51.57 50. 19.37 20110 ERE 1.30 369.8 02.81 0 POL-84.93 (-10.54 8-302.3 -334 -255.2 -740.98 -1014.2 -160.1 0 2-260.7 -625.5 -246.9 -187.9 126.6 0 166.3 33.30 108.1 42.59 92.36 158.7 -13.8 202.7 173.51 114.60 0 108.9 130.58 1000 HD 180.66 111.3 HO 260.57 H 116.737 206.30 OID 180.5) 27.15 113.4 293.3 117.9 142.3 del 60.75 89.96 146.45 52.92 68.85 161 ( 131.0 303.300 68.70 Hid 138.8 DH 29.09 STUIT WAUTO; DI MAGYOOSHEHT Substance (kj/mol) (kj/mol) (i/mol-K) LI (aq)MATC-278.5-273.4 12.20 Li* (g) LICI(s) Magnesium Mg(g) Mg(s) MgCl₂(s) MgO(s) Mg(OH)₂(s) Manganese Mn(g) Mn(s) MnO(s) MnO₂ (s) MnO4 (aq) Mercury Hg(g) Hg(1) HgCl₂(s) Hg₂Cl₂ (s) Nickel Ni(g) Ni(s) NiCl₂(s) NIO(s) Nitrogen N(g) N₂ (8) NH3(aq) NH3(g) NH, (aq) N₂H₂(8) NH₂CN(S) NH₂Cl(s) NH₂NO3(s) NO(g) NO₂(8) N₂O(g) N₂O4(8) NOCI(g) HNO3(aq) HNO3 (8) 686725) 648.51.833,00 TA -408.3 147.1 0 -641.6 -601.8 -924.7 280.7 0 -385.2 -519.6 -541.4 60.83 0 -230.1 -264.9 429.7 0 -305.3 -239.7 472.7 0 -80.29 -46.19 -132.5 42 Eta 95.40 0.4 -314.4 8.150.0 -365.6 90.37 33.84 81.6 9.66 52.6 -206.6 -134.3 (lo 112.5 0 -592.1 -569.6 -833.7 238.5 0 -362.9 -464.8 -447.2 31.76 0 -184.0 -210.5 384.5 0 -259.0 -211.7 455.5 0 -26.50 -16.66 -79.31 159.4 -203.0 -184.0 86.71 51.84 103.59 98.28 66.3 -110.5 -73.94 148.6 32.51 89.6 26.8 63.24 173.6 32.0 59.7 53.14 191.2 174.89 77.40 144.5 192.5 182.1 29.9 97.65 37.99 153.3 191.50 111.3 192.5 113.4 238.5 94.6 151 210.620 240.45 220.0 304.3 264 146 266.4 Substance Oxygen O(g) 0₂(8) 03(8) OH (aq) H₂O(g) H₂O(1) H₂O₂(8) H₂O₂(1) Phosphorus P(g) P₂(8) P4(8) P₁(s, red) P,(s, white) PC13 (8) PC13 (1) PFs (8) PH3(g) P406(S) PO10(S) POCI3 (8) POCI (1) H₂PO₂(aq) Potassium K(g) K(s) K* (aq) K*(8) KCI(s) KCIO3(s) KCIO3(aq) K₂CO3(s) KNO3(s) K₂O(s) KO₂ (s) K₂O₂ (s) KOH(s) KOH(aq) Rubidium Rb(g) Rb(s) RbCl(s) RbCIO3(s) JUS AHUI (kj/mol) 1247.5 0 142.3 -230.0 -285.83 -136.10 -187.8 316.4 144.3 58.9 -17.46 0 -241.82-228.57 -288.07 -319.6 -1594.4 5.4 -1640.1 -2940.1 -542.2 -597.0 -1288.3 89.99 0 -252.4 514.2 -435.9 -391.2 -349.5 -1150.18 -492.70 -363.2 -284.5 -495.8 -424.7 -482.4 APPENDIX C Thermodynamic Quantities for Selected Substances at 298.15 K (25 °C) 85.8 0 -430.5 -392.4 AG; SU (kj/mol) (i/mol-K) 230.1 0 163.4 -157.3 -237.13 -105.48 -120.4 280.0 103.7 24.4 -12.03 0 -269.6 -272.4 -1520.7 13.4 61.17 0 -283.3 481.2 161.0 205.0 237.6 -10.7 H-408.3 -289.9 -284.9 -1064.58 -393.13 -322.1 -240.6 -429.8 -378.9. -440.5 Conical 188.83 69.91 232.9 109.6 55.8 0 -412.0 -292.0 163.2 218.1 280 -2675.2 228.9 11-502.5 325 H-520.9 222 1-1142.6 158.2 22.85 41.08 311.7 217 300.8 210.2 160.2 64.67 102.5 154.5 82.7 143.0 265.7 155.44 132.9 94.14 122.5 113.0 78.91 91.6 CHETICALO 170.0 76.78 92 152 Substance Scandium Sc(g) Sc(s) and Selenium H₂Se(g) Silicon Si(g) Si(s) SIC(s) SIC14(1) SiO₂ (s, quartz) Silver Ag(s) Ag* (aq) AgCl(s) Ag₂O(s) AgNO3(s) Sodium Na(g) Na(s) Na* (aq) Na' (g) NaBr(aq) NaBr(s) Na₂CO3(s) NaCl(aq) NaCl(g) NaCl(s) NaHCO3(s) NaNO3(aq) NaNO3(s) NaOH(aq) NaOH(s) Na₂SO4(s) Strontium Sro(s) Sr(g) Sulfur S(s, rhombic) S8(8) SO₂(8) SO3(8) SO2 (aq) ΔΗ, (kj/mol) 377.8 200 29.7 368.2 0 -73.22 -640.1 1-910.9 0 105.90 -127.0 -31.05 -124.4 107.7 0 -240.1 609.3 -360.6 -361.4 -1130.9 -407.1 -181.4 -410.9 -947.7 -446.2 -467.9 -469.6 -425.6 -1387.1 -592.0 164.4 0 102.3 -296.9 -395.2 -909.3 AG; (kj/mol) 336.1 0 15.9 323.9 0 -70.85 -572.8 -856.5 0 77.11 -109.70 -11.20 -33.41 77.3 0 -261.9 574.3 -364.7 -349.3 -1047.7 -393.0 -201.3 -384.0 -851.8 -372.4 -367.0 -419.2 -379.5 -1270.2 -561.9 110.0 0 49.7 -300.4 -370.4 -744.5 S' (i/mol-K) 174.7 34.6 219.0 167.8 18.7 16.61 239.3 41.84 42.55 73.93 96.11 121.3 140.9 153.7 51.45 59.0 148.0 141.00 86.82 136.0 115.5 229.8 1215 72.33 102.1 207 116.5 49.8 64.46 149.6 54.9 164.6 31.88 430.9 248.5 256.2 20.1 1216 APPENDIX C Thermodynamic Quantities for Selected Substances at 298.15 K (25 °C) Substance SOCI₂(1) H₂S(8) H₂SO4(aq) H₂SO4(1) Titanium Ti(g) Ti(s) TiCl (8) TICI (1) TiO₂ (s) AH; AG (kj/mol) Cha(kj/mol) -245.6 -20.17 -909.3 -814.0 468 0 -763.2 -804.2 -944.7 - -33.01 -744.5 -689.9 422 0 -726.8 -728.1 -889.4 S (i/mol-K)de -bto 205.6 20.1 156.1 180.3 insis nooill2 30.76 354.9 221.9 50.29 ALDIZ Substance Vanadium V(g) 0.fat V(s) 0.205 Zinc Zn(g) Zn(s) ZnCl₂(s) ZnO(s) 10.08 201 AH; (m(kj/mol) 1514.2 0 130.7 0 -415.1 -348.0 X2 BST AG; ((kj/mol) 25453.1 00 0.065 95.2 0 -369.4 -318.2 S' (j/mol-K) 182.2 28.9 160.9 41.63 111.5 43.9 1. Using data in Appendix C, calculate AH, AS', and AG at 298K for each of the following reactions. Indicate whether the reaction is spontaneous at 298K under standard conditions. (a) Ti (s) + 2 Cl₂(g) → TiCl4 (1) (b) HCI (aq) + NaOH (aq) → NaCl (aq) + H₂O (1) (c) CF4 (g) + 2 H₂ (g) → C(s) + 4 HF (g) (d) Na₂CO3 (s) + 2 HNO3(aq) → 2 NaNO3(aq) + CO₂ (g) + H₂O (1) 1. Using data in Appendix C, calculate AH, AS', and AG at 298K for each of the following reactions. Indicate whether the reaction is spontaneous at 298K under standard conditions. (a) Ti (s) + 2 Cl₂(g) → TiCl4 (1) (b) HCI (aq) + NaOH (aq) → NaCl (aq) + H₂O (1) (c) CF4 (g) + 2 H₂ (g) → C(s) + 4 HF (g) (d) Na₂CO3 (s) + 2 HNO3(aq) → 2 NaNO3(aq) + CO₂ (g) + H₂O (1) THERMODYNAMIC QUANTITIES FOR SELECTED SUBSTANCES AT 298.15 K (25 °C) Substance Aluminum Al(s) AICI3(s) Al₂O3(s) Barium Ba(s) BaCO3(s) BaO(s) Beryllium Be(s) BeO(s) Be (OH)2 (s) Bromine Br(g) Br (aq) Br₂(8) Br₂(1) HBr(g) Calcium Ca(g) Ca(s) CaCO3(s, calcite) CaCl₂(s) CaF₂(s) CaO(s) Ca(OH)2(s) CaSO4(s) Carbon C(g) C(s, diamond) C(s, graphite) CC14(8) CC1₂ (1) CF4(8) CH₂(8) AH; (kj/mol) 0 -705.6 -1669.8 0 -1216.3 -553.5 0 -608.4 -905.8 111.8 - 120.9 30.71 -36.23 179.3 0 -1207.1 -795.8 -1219.6 -635.5 -986.2 -1434.0 9718.4 1.88 0 -106.7 -139.3 -679.9 -74.8 AG; (kj/mol) 0 -630.0 -1576.5 0 - 1137.6 -525.1 0 -579.1 -817.9 82.38 - 102.8 3.14 0 -53.22 145.5 0 -1128.76 -748.1 -1167.3 -604.17 -898.5 -1321.8 672.9 2.84 0 -64.0 -68.6 -635.1 -50.8 S (j/mol-K) 28.32 109.3 51.00 63.2 112.1 70.42 9.44 13.77 50.21 174.9 80.71 6H 245.3 152.3 198.49 154.8 41.4 92.88 104.6 68.87 39.75 83.4 106.7 158.0 309.4 214.4 262.3 186.3 2.43 5.69 Will Substance C₂H₂(8) C₂H4(8) C₂H6(8) C3H8(8) C4H10(8) C4H10(1) C6H6(8) C6H6(1) CH₂OH(g) CH₂OH(1) C₂H5OH (8) C₂H₂OH(1) C6H12O6(S) CO(g) CO₂(8) CH3COOH(1) Cesium08 Cs(g) Cs(1) Cs(s) ELLIPS CsCl(s) Chlorine CI(g) HW CI (aq) Cl₂(8) 11.8 HCl(aq) HCI(g) Chromium Cr(g) Cr(s) E Cr₂O3(s) Cobalt Co(g) Co(s) B AH; (kj/mol) 226.77 52.30 -84.68 -103.85 -124.73 -147.6 82.9 49.0 -201.2 -238.6 al-235.1 -277.7 -1273.02 -110.5 06-393.5 -487.0 76.50 2.09 1200 -442.8 121.7 SHOO 1-167.2 -92.30 397.5 22000 -1139.7 APPENDIX C 439 0 AG; (kj/mol) 209.2 68.11 -32.89 -23.47 -15.71 -15.0 129.7 124.5 -161.9 -166.23 08-168.5 1-174.76 25-910.4 -137.2 40-394.4 -392.4 8-167.2-131.2 49.53 08 0.03 eat200 -414.4 105.7 150 2-131.2 -95.27 D 352.6 LABO -1058.1 EXIDE 393 0 S' (j/mol-K) 200.8 219.4 229.5 269.9 310.0 231.0 269.2 172.8 237.6 126.8 282.7 160.7 212.1 197.9 213.6 159.8 175.6 92.07 85.15 101.2 165.2 56.5 222.96 56.5 186.69 174.2 23.6 81.2 179 28.4 121 THERMODYNAMIC QUANTITIES FOR SELECTED SUBSTANCES AT 298.15 K (25 °C) Substance Aluminum Al(s) AICI3(s) Al₂O3(s) Barium Ba(s) BaCO3(s) BaO(s) Beryllium Be(s) BeO(s) Be (OH)2 (s) Bromine Br(g) Br (aq) Br₂(8) Br₂(1) HBr(g) Calcium Ca(g) Ca(s) CaCO3(s, calcite) CaCl₂(s) CaF₂(s) CaO(s) Ca(OH)2(s) CaSO4(s) Carbon C(g) C(s, diamond) C(s, graphite) CC14(8) CC1₂ (1) CF4(8) CH₂(8) AH; (kj/mol) 0 -705.6 -1669.8 0 -1216.3 -553.5 0 -608.4 -905.8 111.8 - 120.9 30.71 -36.23 179.3 0 -1207.1 -795.8 -1219.6 -635.5 -986.2 -1434.0 9718.4 1.88 0 -106.7 -139.3 -679.9 -74.8 AG; (kj/mol) 0 -630.0 -1576.5 0 - 1137.6 -525.1 0 -579.1 -817.9 82.38 - 102.8 3.14 0 -53.22 145.5 0 -1128.76 -748.1 -1167.3 -604.17 -898.5 -1321.8 672.9 2.84 0 -64.0 -68.6 -635.1 -50.8 S (j/mol-K) 28.32 109.3 51.00 63.2 112.1 70.42 9.44 13.77 50.21 174.9 80.71 6H 245.3 152.3 198.49 154.8 41.4 92.88 104.6 68.87 39.75 83.4 106.7 158.0 309.4 214.4 262.3 186.3 2.43 5.69 Will Substance C₂H₂(8) C₂H4(8) C₂H6(8) C3H8(8) C4H10(8) C4H10(1) C6H6(8) C6H6(1) CH₂OH(g) CH₂OH(1) C₂H5OH (8) C₂H₂OH(1) C6H12O6(S) CO(g) CO₂(8) CH3COOH(1) Cesium08 Cs(g) Cs(1) Cs(s) ELLIPS CsCl(s) Chlorine CI(g) HW CI (aq) Cl₂(8) 11.8 HCl(aq) HCI(g) Chromium Cr(g) Cr(s) E Cr₂O3(s) Cobalt Co(g) Co(s) B AH; (kj/mol) 226.77 52.30 -84.68 -103.85 -124.73 -147.6 82.9 49.0 -201.2 -238.6 al-235.1 -277.7 -1273.02 -110.5 06-393.5 -487.0 76.50 2.09 1200 -442.8 121.7 SHOO 1-167.2 -92.30 397.5 22000 -1139.7 APPENDIX C 439 0 AG; (kj/mol) 209.2 68.11 -32.89 -23.47 -15.71 -15.0 129.7 124.5 -161.9 -166.23 08-168.5 1-174.76 25-910.4 -137.2 40-394.4 -392.4 8-167.2-131.2 49.53 08 0.03 eat200 -414.4 105.7 150 2-131.2 -95.27 D 352.6 LABO -1058.1 EXIDE 393 0 S' (j/mol-K) 200.8 219.4 229.5 269.9 310.0 231.0 269.2 172.8 237.6 126.8 282.7 160.7 212.1 197.9 213.6 159.8 175.6 92.07 85.15 101.2 165.2 56.5 222.96 56.5 186.69 174.2 23.6 81.2 179 28.4 121 1214 APPENDIX C Thermodynamic Quantities for Selected Substances at 298.15 K (25 °C) Substance Copper Cu(g) Cu(s) CuCl₂(s) CuO(s) Cu₂O(s) Fluorine F(g) F (aq) F₂(8) HF(g) Hydrogen H(g) H*(aq) H*(8) H₂(8) ES lodine 051 I(g) 58 (8) 00 12(8) LESS 1₂(s) e HI(g) E Iron Fe(g) Fe(s) 21 Fe²+ (aq) Fe³+ (aq) FeCl₂(s) FeCl3(s) FeO(s) zal Fe₂O3(s) Fe3O4(s) FeS₂(s) Lead Pb(s) PbBr₂(S) PbCO3(s) 2 Pb(NO3)2(aq) Pb(NO3)2(S) PbO(s) Lithium Li(g) Li(s) AH; (kj/mol) 338.4 0 -205.9 -156.1 -170.7 80.0 -332.6 0 -268.61 217.94 0 1536.2 0 28106.60 8-55.19 A0162.25 STEL O 25.94 415.5 EERO 20.0-87.86 (-47.69 -341.8 -400 -271.9 -822.16 -1117.1 1-171.5 0 -277.4 -699.1 -421.3 -451.9 -217.3 159.3 0 (fo AG; PROSPERT (kj/mol) (i/mol-K) 298.6 0 -161.7 -128.3 -147.9 61.9 -278.8 0 88-270.70 203.26 0 1517.0 8.1000 Le 70.16 1.-51.57 50. 19.37 20110 ERE 1.30 369.8 02.81 0 POL-84.93 (-10.54 8-302.3 -334 -255.2 -740.98 -1014.2 -160.1 0 2-260.7 -625.5 -246.9 -187.9 126.6 0 166.3 33.30 108.1 42.59 92.36 158.7 -13.8 202.7 173.51 114.60 0 108.9 130.58 1000 HD 180.66 111.3 HO 260.57 H 116.737 206.30 OID 180.5) 27.15 113.4 293.3 117.9 142.3 del 60.75 89.96 146.45 52.92 68.85 161 ( 131.0 303.300 68.70 Hid 138.8 DH 29.09 STUIT WAUTO; DI MAGYOOSHEHT Substance (kj/mol) (kj/mol) (i/mol-K) LI (aq)MATC-278.5-273.4 12.20 Li* (g) LICI(s) Magnesium Mg(g) Mg(s) MgCl₂(s) MgO(s) Mg(OH)₂(s) Manganese Mn(g) Mn(s) MnO(s) MnO₂ (s) MnO4 (aq) Mercury Hg(g) Hg(1) HgCl₂(s) Hg₂Cl₂ (s) Nickel Ni(g) Ni(s) NiCl₂(s) NIO(s) Nitrogen N(g) N₂ (8) NH3(aq) NH3(g) NH, (aq) N₂H₂(8) NH₂CN(S) NH₂Cl(s) NH₂NO3(s) NO(g) NO₂(8) N₂O(g) N₂O4(8) NOCI(g) HNO3(aq) HNO3 (8) 686725) 648.51.833,00 TA -408.3 147.1 0 -641.6 -601.8 -924.7 280.7 0 -385.2 -519.6 -541.4 60.83 0 -230.1 -264.9 429.7 0 -305.3 -239.7 472.7 0 -80.29 -46.19 -132.5 42 Eta 95.40 0.4 -314.4 8.150.0 -365.6 90.37 33.84 81.6 9.66 52.6 -206.6 -134.3 (lo 112.5 0 -592.1 -569.6 -833.7 238.5 0 -362.9 -464.8 -447.2 31.76 0 -184.0 -210.5 384.5 0 -259.0 -211.7 455.5 0 -26.50 -16.66 -79.31 159.4 -203.0 -184.0 86.71 51.84 103.59 98.28 66.3 -110.5 -73.94 148.6 32.51 89.6 26.8 63.24 173.6 32.0 59.7 53.14 191.2 174.89 77.40 144.5 192.5 182.1 29.9 97.65 37.99 153.3 191.50 111.3 192.5 113.4 238.5 94.6 151 210.620 240.45 220.0 304.3 264 146 266.4 1214 APPENDIX C Thermodynamic Quantities for Selected Substances at 298.15 K (25 °C) Substance Copper Cu(g) Cu(s) CuCl₂(s) CuO(s) Cu₂O(s) Fluorine F(g) F (aq) F₂(8) HF(g) Hydrogen H(g) H*(aq) H*(8) H₂(8) ES lodine 051 I(g) 58 (8) 00 12(8) LESS 1₂(s) e HI(g) E Iron Fe(g) Fe(s) 21 Fe²+ (aq) Fe³+ (aq) FeCl₂(s) FeCl3(s) FeO(s) zal Fe₂O3(s) Fe3O4(s) FeS₂(s) Lead Pb(s) PbBr₂(S) PbCO3(s) 2 Pb(NO3)2(aq) Pb(NO3)2(S) PbO(s) Lithium Li(g) Li(s) AH; (kj/mol) 338.4 0 -205.9 -156.1 -170.7 80.0 -332.6 0 -268.61 217.94 0 1536.2 0 28106.60 8-55.19 A0162.25 STEL O 25.94 415.5 EERO 20.0-87.86 (-47.69 -341.8 -400 -271.9 -822.16 -1117.1 1-171.5 0 -277.4 -699.1 -421.3 -451.9 -217.3 159.3 0 (fo AG; PROSPERT (kj/mol) (i/mol-K) 298.6 0 -161.7 -128.3 -147.9 61.9 -278.8 0 88-270.70 203.26 0 1517.0 8.1000 Le 70.16 1.-51.57 50. 19.37 20110 ERE 1.30 369.8 02.81 0 POL-84.93 (-10.54 8-302.3 -334 -255.2 -740.98 -1014.2 -160.1 0 2-260.7 -625.5 -246.9 -187.9 126.6 0 166.3 33.30 108.1 42.59 92.36 158.7 -13.8 202.7 173.51 114.60 0 108.9 130.58 1000 HD 180.66 111.3 HO 260.57 H 116.737 206.30 OID 180.5) 27.15 113.4 293.3 117.9 142.3 del 60.75 89.96 146.45 52.92 68.85 161 ( 131.0 303.300 68.70 Hid 138.8 DH 29.09 STUIT WAUTO; DI MAGYOOSHEHT Substance (kj/mol) (kj/mol) (i/mol-K) LI (aq)MATC-278.5-273.4 12.20 Li* (g) LICI(s) Magnesium Mg(g) Mg(s) MgCl₂(s) MgO(s) Mg(OH)₂(s) Manganese Mn(g) Mn(s) MnO(s) MnO₂ (s) MnO4 (aq) Mercury Hg(g) Hg(1) HgCl₂(s) Hg₂Cl₂ (s) Nickel Ni(g) Ni(s) NiCl₂(s) NIO(s) Nitrogen N(g) N₂ (8) NH3(aq) NH3(g) NH, (aq) N₂H₂(8) NH₂CN(S) NH₂Cl(s) NH₂NO3(s) NO(g) NO₂(8) N₂O(g) N₂O4(8) NOCI(g) HNO3(aq) HNO3 (8) 686725) 648.51.833,00 TA -408.3 147.1 0 -641.6 -601.8 -924.7 280.7 0 -385.2 -519.6 -541.4 60.83 0 -230.1 -264.9 429.7 0 -305.3 -239.7 472.7 0 -80.29 -46.19 -132.5 42 Eta 95.40 0.4 -314.4 8.150.0 -365.6 90.37 33.84 81.6 9.66 52.6 -206.6 -134.3 (lo 112.5 0 -592.1 -569.6 -833.7 238.5 0 -362.9 -464.8 -447.2 31.76 0 -184.0 -210.5 384.5 0 -259.0 -211.7 455.5 0 -26.50 -16.66 -79.31 159.4 -203.0 -184.0 86.71 51.84 103.59 98.28 66.3 -110.5 -73.94 148.6 32.51 89.6 26.8 63.24 173.6 32.0 59.7 53.14 191.2 174.89 77.40 144.5 192.5 182.1 29.9 97.65 37.99 153.3 191.50 111.3 192.5 113.4 238.5 94.6 151 210.620 240.45 220.0 304.3 264 146 266.4 Substance Oxygen O(g) 0₂(8) 03(8) OH (aq) H₂O(g) H₂O(1) H₂O₂(8) H₂O₂(1) Phosphorus P(g) P₂(8) P4(8) P₁(s, red) P,(s, white) PC13 (8) PC13 (1) PFs (8) PH3(g) P406(S) PO10(S) POCI3 (8) POCI (1) H₂PO₂(aq) Potassium K(g) K(s) K* (aq) K*(8) KCI(s) KCIO3(s) KCIO3(aq) K₂CO3(s) KNO3(s) K₂O(s) KO₂ (s) K₂O₂ (s) KOH(s) KOH(aq) Rubidium Rb(g) Rb(s) RbCl(s) RbCIO3(s) JUS AHUI (kj/mol) 1247.5 0 142.3 -230.0 -285.83 -136.10 -187.8 316.4 144.3 58.9 -17.46 0 -241.82-228.57 -288.07 -319.6 -1594.4 5.4 -1640.1 -2940.1 -542.2 -597.0 -1288.3 89.99 0 -252.4 514.2 -435.9 -391.2 -349.5 -1150.18 -492.70 -363.2 -284.5 -495.8 -424.7 -482.4 APPENDIX C Thermodynamic Quantities for Selected Substances at 298.15 K (25 °C) 85.8 0 -430.5 -392.4 AG; SU (kj/mol) (i/mol-K) 230.1 0 163.4 -157.3 -237.13 -105.48 -120.4 280.0 103.7 24.4 -12.03 0 -269.6 -272.4 -1520.7 13.4 61.17 0 -283.3 481.2 161.0 205.0 237.6 -10.7 H-408.3 -289.9 -284.9 -1064.58 -393.13 -322.1 -240.6 -429.8 -378.9. -440.5 Conical 188.83 69.91 232.9 109.6 55.8 0 -412.0 -292.0 163.2 218.1 280 -2675.2 228.9 11-502.5 325 H-520.9 222 1-1142.6 158.2 22.85 41.08 311.7 217 300.8 210.2 160.2 64.67 102.5 154.5 82.7 143.0 265.7 155.44 132.9 94.14 122.5 113.0 78.91 91.6 CHETICALO 170.0 76.78 92 152 Substance Scandium Sc(g) Sc(s) and Selenium H₂Se(g) Silicon Si(g) Si(s) SIC(s) SIC14(1) SiO₂ (s, quartz) Silver Ag(s) Ag* (aq) AgCl(s) Ag₂O(s) AgNO3(s) Sodium Na(g) Na(s) Na* (aq) Na' (g) NaBr(aq) NaBr(s) Na₂CO3(s) NaCl(aq) NaCl(g) NaCl(s) NaHCO3(s) NaNO3(aq) NaNO3(s) NaOH(aq) NaOH(s) Na₂SO4(s) Strontium Sro(s) Sr(g) Sulfur S(s, rhombic) S8(8) SO₂(8) SO3(8) SO2 (aq) ΔΗ, (kj/mol) 377.8 200 29.7 368.2 0 -73.22 -640.1 1-910.9 0 105.90 -127.0 -31.05 -124.4 107.7 0 -240.1 609.3 -360.6 -361.4 -1130.9 -407.1 -181.4 -410.9 -947.7 -446.2 -467.9 -469.6 -425.6 -1387.1 -592.0 164.4 0 102.3 -296.9 -395.2 -909.3 AG; (kj/mol) 336.1 0 15.9 323.9 0 -70.85 -572.8 -856.5 0 77.11 -109.70 -11.20 -33.41 77.3 0 -261.9 574.3 -364.7 -349.3 -1047.7 -393.0 -201.3 -384.0 -851.8 -372.4 -367.0 -419.2 -379.5 -1270.2 -561.9 110.0 0 49.7 -300.4 -370.4 -744.5 S' (i/mol-K) 174.7 34.6 219.0 167.8 18.7 16.61 239.3 41.84 42.55 73.93 96.11 121.3 140.9 153.7 51.45 59.0 148.0 141.00 86.82 136.0 115.5 229.8 1215 72.33 102.1 207 116.5 49.8 64.46 149.6 54.9 164.6 31.88 430.9 248.5 256.2 20.1 Substance Oxygen O(g) 0₂(8) 03(8) OH (aq) H₂O(g) H₂O(1) H₂O₂(8) H₂O₂(1) Phosphorus P(g) P₂(8) P4(8) P₁(s, red) P,(s, white) PC13 (8) PC13 (1) PFs (8) PH3(g) P406(S) PO10(S) POCI3 (8) POCI (1) H₂PO₂(aq) Potassium K(g) K(s) K* (aq) K*(8) KCI(s) KCIO3(s) KCIO3(aq) K₂CO3(s) KNO3(s) K₂O(s) KO₂ (s) K₂O₂ (s) KOH(s) KOH(aq) Rubidium Rb(g) Rb(s) RbCl(s) RbCIO3(s) JUS AHUI (kj/mol) 1247.5 0 142.3 -230.0 -285.83 -136.10 -187.8 316.4 144.3 58.9 -17.46 0 -241.82-228.57 -288.07 -319.6 -1594.4 5.4 -1640.1 -2940.1 -542.2 -597.0 -1288.3 89.99 0 -252.4 514.2 -435.9 -391.2 -349.5 -1150.18 -492.70 -363.2 -284.5 -495.8 -424.7 -482.4 APPENDIX C Thermodynamic Quantities for Selected Substances at 298.15 K (25 °C) 85.8 0 -430.5 -392.4 AG; SU (kj/mol) (i/mol-K) 230.1 0 163.4 -157.3 -237.13 -105.48 -120.4 280.0 103.7 24.4 -12.03 0 -269.6 -272.4 -1520.7 13.4 61.17 0 -283.3 481.2 161.0 205.0 237.6 -10.7 H-408.3 -289.9 -284.9 -1064.58 -393.13 -322.1 -240.6 -429.8 -378.9. -440.5 Conical 188.83 69.91 232.9 109.6 55.8 0 -412.0 -292.0 163.2 218.1 280 -2675.2 228.9 11-502.5 325 H-520.9 222 1-1142.6 158.2 22.85 41.08 311.7 217 300.8 210.2 160.2 64.67 102.5 154.5 82.7 143.0 265.7 155.44 132.9 94.14 122.5 113.0 78.91 91.6 CHETICALO 170.0 76.78 92 152 Substance Scandium Sc(g) Sc(s) and Selenium H₂Se(g) Silicon Si(g) Si(s) SIC(s) SIC14(1) SiO₂ (s, quartz) Silver Ag(s) Ag* (aq) AgCl(s) Ag₂O(s) AgNO3(s) Sodium Na(g) Na(s) Na* (aq) Na' (g) NaBr(aq) NaBr(s) Na₂CO3(s) NaCl(aq) NaCl(g) NaCl(s) NaHCO3(s) NaNO3(aq) NaNO3(s) NaOH(aq) NaOH(s) Na₂SO4(s) Strontium Sro(s) Sr(g) Sulfur S(s, rhombic) S8(8) SO₂(8) SO3(8) SO2 (aq) ΔΗ, (kj/mol) 377.8 200 29.7 368.2 0 -73.22 -640.1 1-910.9 0 105.90 -127.0 -31.05 -124.4 107.7 0 -240.1 609.3 -360.6 -361.4 -1130.9 -407.1 -181.4 -410.9 -947.7 -446.2 -467.9 -469.6 -425.6 -1387.1 -592.0 164.4 0 102.3 -296.9 -395.2 -909.3 AG; (kj/mol) 336.1 0 15.9 323.9 0 -70.85 -572.8 -856.5 0 77.11 -109.70 -11.20 -33.41 77.3 0 -261.9 574.3 -364.7 -349.3 -1047.7 -393.0 -201.3 -384.0 -851.8 -372.4 -367.0 -419.2 -379.5 -1270.2 -561.9 110.0 0 49.7 -300.4 -370.4 -744.5 S' (i/mol-K) 174.7 34.6 219.0 167.8 18.7 16.61 239.3 41.84 42.55 73.93 96.11 121.3 140.9 153.7 51.45 59.0 148.0 141.00 86.82 136.0 115.5 229.8 1215 72.33 102.1 207 116.5 49.8 64.46 149.6 54.9 164.6 31.88 430.9 248.5 256.2 20.1 1216 APPENDIX C Thermodynamic Quantities for Selected Substances at 298.15 K (25 °C) Substance SOCI₂(1) H₂S(8) H₂SO4(aq) H₂SO4(1) Titanium Ti(g) Ti(s) TiCl (8) TICI (1) TiO₂ (s) AH; AG (kj/mol) Cha(kj/mol) -245.6 -20.17 -909.3 -814.0 468 0 -763.2 -804.2 -944.7 - -33.01 -744.5 -689.9 422 0 -726.8 -728.1 -889.4 S (i/mol-K)de -bto 205.6 20.1 156.1 180.3 insis nooill2 30.76 354.9 221.9 50.29 ALDIZ Substance Vanadium V(g) 0.fat V(s) 0.205 Zinc Zn(g) Zn(s) ZnCl₂(s) ZnO(s) 10.08 201 AH; (m(kj/mol) 1514.2 0 130.7 0 -415.1 -348.0 X2 BST AG; ((kj/mol) 25453.1 00 0.065 95.2 0 -369.4 -318.2 S' (j/mol-K) 182.2 28.9 160.9 41.63 111.5 43.9 1216 APPENDIX C Thermodynamic Quantities for Selected Substances at 298.15 K (25 °C) Substance SOCI₂(1) H₂S(8) H₂SO4(aq) H₂SO4(1) Titanium Ti(g) Ti(s) TiCl (8) TICI (1) TiO₂ (s) AH; AG (kj/mol) Cha(kj/mol) -245.6 -20.17 -909.3 -814.0 468 0 -763.2 -804.2 -944.7 - -33.01 -744.5 -689.9 422 0 -726.8 -728.1 -889.4 S (i/mol-K)de -bto 205.6 20.1 156.1 180.3 insis nooill2 30.76 354.9 221.9 50.29 ALDIZ Substance Vanadium V(g) 0.fat V(s) 0.205 Zinc Zn(g) Zn(s) ZnCl₂(s) ZnO(s) 10.08 201 AH; (m(kj/mol) 1514.2 0 130.7 0 -415.1 -348.0 X2 BST AG; ((kj/mol) 25453.1 00 0.065 95.2 0 -369.4 -318.2 S' (j/mol-K) 182.2 28.9 160.9 41.63 111.5 43.9

Answer rating: 100% (QA)

Sure we can use the data provided in Appendix C to calculate the standard enthalpy change H the standard entropy change S and the standard Gibbs free ... View the full answer