Question: 1. Using data in Appendix C, calculate AH, AS', and AG at 298K for each of the following reactions. Indicate whether the reaction is

THERMODYNAMIC QUANTITIES FOR SELECTED SUBSTANCES AT 298.15 K (25 C) Substance Aluminum Al(s) AICI3(s) AlO3(s)

1214 APPENDIX C Thermodynamic Quantities for Selected Substances at 298.15 K (25 C) Substance Copper Cu(g)

Substance Oxygen O(g) 0(8) 03(8) OH (aq) HO(g) HO(1) HO(8) HO(1) Phosphorus P(g) P(8) P4(8) P(s, red) P,(s,

1216 APPENDIX C Thermodynamic Quantities for Selected Substances at 298.15 K (25 C) Substance SOCI(1) HS(8)

1. Using data in Appendix C, calculate AH, AS', and AG at 298K for each of the following reactions. Indicate whether the reaction is spontaneous at 298K under standard conditions. (a) Ti (s) + 2 Cl(g) TiCl4 (1) (b) HCI (aq) + NaOH (aq) NaCl (aq) + HO (1) (c) CF4 (g) + 2 H (g) C(s) + 4 HF (g) (d) NaCO3 (s) + 2 HNO3(aq) 2 NaNO3(aq) + CO (g) + HO (1) THERMODYNAMIC QUANTITIES FOR SELECTED SUBSTANCES AT 298.15 K (25 C) Substance Aluminum Al(s) AICI3(s) AlO3(s) Barium Ba(s) BaCO3(s) BaO(s) Beryllium Be(s) BeO(s) Be (OH)2 (s) Bromine Br(g) Br (aq) Br(8) Br(1) HBr(g) Calcium Ca(g) Ca(s) CaCO3(s, calcite) CaCl(s) CaF(s) CaO(s) Ca(OH)2(s) CaSO4(s) Carbon C(g) C(s, diamond) C(s, graphite) CC14(8) CC1 (1) CF4(8) CH(8) AH; (kj/mol) 0 -705.6 -1669.8 0 -1216.3 -553.5 0 -608.4 -905.8 111.8 - 120.9 30.71 -36.23 179.3 0 -1207.1 -795.8 -1219.6 -635.5 -986.2 -1434.0 9718.4 1.88 0 -106.7 -139.3 -679.9 -74.8 AG; (kj/mol) 0 -630.0 -1576.5 0 - 1137.6 -525.1 0 -579.1 -817.9 82.38 - 102.8 3.14 0 -53.22 145.5 0 -1128.76 -748.1 -1167.3 -604.17 -898.5 -1321.8 672.9 2.84 0 -64.0 -68.6 -635.1 -50.8 S (j/mol-K) 28.32 109.3 51.00 63.2 112.1 70.42 9.44 13.77 50.21 174.9 80.71 6H 245.3 152.3 198.49 154.8 41.4 92.88 104.6 68.87 39.75 83.4 106.7 158.0 309.4 214.4 262.3 186.3 2.43 5.69 Will Substance CH(8) CH4(8) CH6(8) C3H8(8) C4H10(8) C4H10(1) C6H6(8) C6H6(1) CHOH(g) CHOH(1) CH5OH (8) CHOH(1) C6H12O6(S) CO(g) CO(8) CH3COOH(1) Cesium08 Cs(g) Cs(1) Cs(s) ELLIPS CsCl(s) Chlorine CI(g) HW CI (aq) Cl(8) 11.8 HCl(aq) HCI(g) Chromium Cr(g) Cr(s) E CrO3(s) Cobalt Co(g) Co(s) B AH; (kj/mol) 226.77 52.30 -84.68 -103.85 -124.73 -147.6 82.9 49.0 -201.2 -238.6 al-235.1 -277.7 -1273.02 -110.5 06-393.5 -487.0 76.50 2.09 1200 -442.8 121.7 SHOO 1-167.2 -92.30 397.5 22000 -1139.7 APPENDIX C 439 0 AG; (kj/mol) 209.2 68.11 -32.89 -23.47 -15.71 -15.0 129.7 124.5 -161.9 -166.23 08-168.5 1-174.76 25-910.4 -137.2 40-394.4 -392.4 8-167.2-131.2 49.53 08 0.03 eat200 -414.4 105.7 150 2-131.2 -95.27 D 352.6 LABO -1058.1 EXIDE 393 0 S' (j/mol-K) 200.8 219.4 229.5 269.9 310.0 231.0 269.2 172.8 237.6 126.8 282.7 160.7 212.1 197.9 213.6 159.8 175.6 92.07 85.15 101.2 165.2 56.5 222.96 56.5 186.69 174.2 23.6 81.2 179 28.4 121 1214 APPENDIX C Thermodynamic Quantities for Selected Substances at 298.15 K (25 C) Substance Copper Cu(g) Cu(s) CuCl(s) CuO(s) CuO(s) Fluorine F(g) F (aq) F(8) HF(g) Hydrogen H(g) H*(aq) H*(8) H(8) ES lodine 051 I(g) 58 (8) 00 12(8) LESS 1(s) e HI(g) E Iron Fe(g) Fe(s) 21 Fe+ (aq) Fe+ (aq) FeCl(s) FeCl3(s) FeO(s) zal FeO3(s) Fe3O4(s) FeS(s) Lead Pb(s) PbBr(S) PbCO3(s) 2 Pb(NO3)2(aq) Pb(NO3)2(S) PbO(s) Lithium Li(g) Li(s) AH; (kj/mol) 338.4 0 -205.9 -156.1 -170.7 80.0 -332.6 0 -268.61 217.94 0 1536.2 0 28106.60 8-55.19 A0162.25 STEL O 25.94 415.5 EERO 20.0-87.86 (-47.69 -341.8 -400 -271.9 -822.16 -1117.1 1-171.5 0 -277.4 -699.1 -421.3 -451.9 -217.3 159.3 0 (fo AG; PROSPERT (kj/mol) (i/mol-K) 298.6 0 -161.7 -128.3 -147.9 61.9 -278.8 0 88-270.70 203.26 0 1517.0 8.1000 Le 70.16 1.-51.57 50. 19.37 20110 ERE 1.30 369.8 02.81 0 POL-84.93 (-10.54 8-302.3 -334 -255.2 -740.98 -1014.2 -160.1 0 2-260.7 -625.5 -246.9 -187.9 126.6 0 166.3 33.30 108.1 42.59 92.36 158.7 -13.8 202.7 173.51 114.60 0 108.9 130.58 1000 HD 180.66 111.3 HO 260.57 H 116.737 206.30 OID 180.5) 27.15 113.4 293.3 117.9 142.3 del 60.75 89.96 146.45 52.92 68.85 161 ( 131.0 303.300 68.70 Hid 138.8 DH 29.09 STUIT WAUTO; DI MAGYOOSHEHT Substance (kj/mol) (kj/mol) (i/mol-K) LI (aq)MATC-278.5-273.4 12.20 Li* (g) LICI(s) Magnesium Mg(g) Mg(s) MgCl(s) MgO(s) Mg(OH)(s) Manganese Mn(g) Mn(s) MnO(s) MnO (s) MnO4 (aq) Mercury Hg(g) Hg(1) HgCl(s) HgCl (s) Nickel Ni(g) Ni(s) NiCl(s) NIO(s) Nitrogen N(g) N (8) NH3(aq) NH3(g) NH, (aq) NH(8) NHCN(S) NHCl(s) NHNO3(s) NO(g) NO(8) NO(g) NO4(8) NOCI(g) HNO3(aq) HNO3 (8) 686725) 648.51.833,00 TA -408.3 147.1 0 -641.6 -601.8 -924.7 280.7 0 -385.2 -519.6 -541.4 60.83 0 -230.1 -264.9 429.7 0 -305.3 -239.7 472.7 0 -80.29 -46.19 -132.5 42 Eta 95.40 0.4 -314.4 8.150.0 -365.6 90.37 33.84 81.6 9.66 52.6 -206.6 -134.3 (lo 112.5 0 -592.1 -569.6 -833.7 238.5 0 -362.9 -464.8 -447.2 31.76 0 -184.0 -210.5 384.5 0 -259.0 -211.7 455.5 0 -26.50 -16.66 -79.31 159.4 -203.0 -184.0 86.71 51.84 103.59 98.28 66.3 -110.5 -73.94 148.6 32.51 89.6 26.8 63.24 173.6 32.0 59.7 53.14 191.2 174.89 77.40 144.5 192.5 182.1 29.9 97.65 37.99 153.3 191.50 111.3 192.5 113.4 238.5 94.6 151 210.620 240.45 220.0 304.3 264 146 266.4 Substance Oxygen O(g) 0(8) 03(8) OH (aq) HO(g) HO(1) HO(8) HO(1) Phosphorus P(g) P(8) P4(8) P(s, red) P,(s, white) PC13 (8) PC13 (1) PFs (8) PH3(g) P406(S) PO10(S) POCI3 (8) POCI (1) HPO(aq) Potassium K(g) K(s) K* (aq) K*(8) KCI(s) KCIO3(s) KCIO3(aq) KCO3(s) KNO3(s) KO(s) KO (s) KO (s) KOH(s) KOH(aq) Rubidium Rb(g) Rb(s) RbCl(s) RbCIO3(s) JUS AHUI (kj/mol) 1247.5 0 142.3 -230.0 -285.83 -136.10 -187.8 316.4 144.3 58.9 -17.46 0 -241.82-228.57 -288.07 -319.6 -1594.4 5.4 -1640.1 -2940.1 -542.2 -597.0 -1288.3 89.99 0 -252.4 514.2 -435.9 -391.2 -349.5 -1150.18 -492.70 -363.2 -284.5 -495.8 -424.7 -482.4 APPENDIX C Thermodynamic Quantities for Selected Substances at 298.15 K (25 C) 85.8 0 -430.5 -392.4 AG; SU (kj/mol) (i/mol-K) 230.1 0 163.4 -157.3 -237.13 -105.48 -120.4 280.0 103.7 24.4 -12.03 0 -269.6 -272.4 -1520.7 13.4 61.17 0 -283.3 481.2 161.0 205.0 237.6 -10.7 H-408.3 -289.9 -284.9 -1064.58 -393.13 -322.1 -240.6 -429.8 -378.9. -440.5 Conical 188.83 69.91 232.9 109.6 55.8 0 -412.0 -292.0 163.2 218.1 280 -2675.2 228.9 11-502.5 325 H-520.9 222 1-1142.6 158.2 22.85 41.08 311.7 217 300.8 210.2 160.2 64.67 102.5 154.5 82.7 143.0 265.7 155.44 132.9 94.14 122.5 113.0 78.91 91.6 CHETICALO 170.0 76.78 92 152 Substance Scandium Sc(g) Sc(s) and Selenium HSe(g) Silicon Si(g) Si(s) SIC(s) SIC14(1) SiO (s, quartz) Silver Ag(s) Ag* (aq) AgCl(s) AgO(s) AgNO3(s) Sodium Na(g) Na(s) Na* (aq) Na' (g) NaBr(aq) NaBr(s) NaCO3(s) NaCl(aq) NaCl(g) NaCl(s) NaHCO3(s) NaNO3(aq) NaNO3(s) NaOH(aq) NaOH(s) NaSO4(s) Strontium Sro(s) Sr(g) Sulfur S(s, rhombic) S8(8) SO(8) SO3(8) SO2 (aq) , (kj/mol) 377.8 200 29.7 368.2 0 -73.22 -640.1 1-910.9 0 105.90 -127.0 -31.05 -124.4 107.7 0 -240.1 609.3 -360.6 -361.4 -1130.9 -407.1 -181.4 -410.9 -947.7 -446.2 -467.9 -469.6 -425.6 -1387.1 -592.0 164.4 0 102.3 -296.9 -395.2 -909.3 AG; (kj/mol) 336.1 0 15.9 323.9 0 -70.85 -572.8 -856.5 0 77.11 -109.70 -11.20 -33.41 77.3 0 -261.9 574.3 -364.7 -349.3 -1047.7 -393.0 -201.3 -384.0 -851.8 -372.4 -367.0 -419.2 -379.5 -1270.2 -561.9 110.0 0 49.7 -300.4 -370.4 -744.5 S' (i/mol-K) 174.7 34.6 219.0 167.8 18.7 16.61 239.3 41.84 42.55 73.93 96.11 121.3 140.9 153.7 51.45 59.0 148.0 141.00 86.82 136.0 115.5 229.8 1215 72.33 102.1 207 116.5 49.8 64.46 149.6 54.9 164.6 31.88 430.9 248.5 256.2 20.1 1216 APPENDIX C Thermodynamic Quantities for Selected Substances at 298.15 K (25 C) Substance SOCI(1) HS(8) HSO4(aq) HSO4(1) Titanium Ti(g) Ti(s) TiCl (8) TICI (1) TiO (s) AH; AG (kj/mol) Cha(kj/mol) -245.6 -20.17 -909.3 -814.0 468 0 -763.2 -804.2 -944.7 - -33.01 -744.5 -689.9 422 0 -726.8 -728.1 -889.4 S (i/mol-K)de -bto 205.6 20.1 156.1 180.3 insis nooill2 30.76 354.9 221.9 50.29 ALDIZ Substance Vanadium V(g) 0.fat V(s) 0.205 Zinc Zn(g) Zn(s) ZnCl(s) ZnO(s) 10.08 201 AH; (m(kj/mol) 1514.2 0 130.7 0 -415.1 -348.0 X2 BST AG; ((kj/mol) 25453.1 00 0.065 95.2 0 -369.4 -318.2 S' (j/mol-K) 182.2 28.9 160.9 41.63 111.5 43.9

Step by Step Solution

★★★★★

3.50 Rating (150 Votes )

There are 3 Steps involved in it

1 Expert Approved Answer

Step: 1 Unlock

Sure we can use the data provided in Appendix C to calculate the standard enthalpy change H the standard entropy change S and the standard Gibbs free ... View full answer

Question Has Been Solved by an Expert!

Get step-by-step solutions from verified subject matter experts

Step: 2 Unlock

Step: 3 Unlock

Students Have Also Explored These Related Chemical Engineering Questions!

Find a such that 4dx=10. (Hint: you may find it helpful to sketch the graph.) a=

Using data from Appendix C, calculate the change in Gibbs free energy for each of the following reactions. In each case indicate whether the reaction is spontaneous at 298 K under standard...

For each of the following reactions, indicate whether the reaction would work well, poorly, or not at all. Formulate alternative products, if appropriate. (a) (b) (c) (d) (e) (f) (g) (h) (i) (j) (k)...

import java.util.ArrayList; import java.util.Map; import java.util.Set; import java.util.TreeMap; /* * * This class contains a map of string keys, representing professors, to an array list of...

1. The student council at Gotham College is made up of four freshmen, five sophomores, six juniors, and seven seniors. A yearbook photographer would like to line up three council members from each...

6.25 Blood pressure A World Health Organization study (the MONICA project) of health in various countries reported that in Canada, systolic blood pressure readings have a mean of 121 and a standard...

Let be a sample space and suppose we have defined a set function, P(), which satisfies the properties P1P3 of Definition 1.10, on that space. Examine whether each of the set functions defined below...

Refer to problem S6.16. If the defective rate was 3.5 % instead of 1.5%, what would be the control limits (z = 3)? In problem S6.16, In the past, the defective rate for your product has been 1.5%....

A corporation with a balance sheet date of December 31 has a foreign long-term liability that is not covered by a foreign exchange contract. The foreign currency amount was converted at the closing...

On April 1, Cyclone Company purchases a trencher for $308,000. The machine is expected to last five years and have a salvage value of $54,000. Compute depreciation expense at December 31 for both the...

Return to Blackboard LUS Waveamer, Vinancial and Managerial, 3e CALCULATOR PRINTER VERSION RACE Multiple Choice Question 102 Sheffield Company uses the units-of-activity method in computing...

Strategic decision-making will determine the direction of any organisation. Some oorganisations make better strategic decisions than others. Various processes exist to make a strategic decision;...

Iqbal Corporation produces and sells a single product, has provided its contribution format income statement for March. Sales (17,000 units) Rs. 2,210,000 Variable Expenses 1,530,000 Contribution...

3.Fresh Foods wants to decrease the total cost of guava. Identify three costs areas - other than price - that Fresh Foods to focus on to decrease total cost. Explain why you choose those cost areas....

i.Suggest at least THREE (3) kinds of analytics and machine learning algorithms that Champo Carpets can use to solve their problems, and in general, for value creation. ii.Explain the data strategy...

While traveling on an assignment that is being paid for by your employer, you visit an area in which you would really like to live but can never find time to visit on your own. You have five days to...

C++ Question 1 The following program asks the user for the current temperature (in Fahrenheit). Add a series of if statements (if with multiple alternatives) so that one of the following messages is...

Design an experiment to demonstrate that RNA transcripts are synthesized in the nucleus of eukaryotes and are subsequently transported to the cytoplasm.

The following processes were all discussed in Chapter 18, "Chemistry of the Environment." Estimate whether the entropy of the system increases or decreases during each process: (a) Photodissociation...

We saw in Chapter 6 that the probability of finding an electron in three-dimensional space depends on what orbital it is in. Look back at Figures 6.19 and 6.22, which show the radial probability...

(a) Precipitation of the group 4 cations of Figure 17.23 requires a basic medium. Why is this so? (b) What is the most significant difference between the sulfides precipitated in group 2 and those...

In what ways does technology have an impact on process design? Layout design?

Describe the approach for process design.

Compare the layout of a supermarket to the layout of a convenience store. Explain the differences you observe.