Question: Consider the kinetic scheme for free-radical polymerization. Demonstrate that when polymer chains terminate at sites located on the surface of the polymerization vessel: kwall

Consider the kinetic scheme for free-radical polymerization. Demonstrate that when polymer chains

Consider the kinetic scheme for free-radical polymerization. Demonstrate that when polymer chains terminate at sites located on the surface of the polymerization vessel: kwall RM P and this is the only mode of termination, then the overall rate of polymer- ization is given by: V, = kpol [M][I] where kpol = 2 kp kal kwall- !!

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