According to the Lindeman criterion, a crystal melts when the RMS dis- placement of its atoms...
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According to the Lindeman criterion, a crystal melts when the RMS dis- placement of its atoms exceeds one-third of the average separation of the atoms. Consider a three-dimensional crystal with separation a, atoms of mass m and a nearest-neighbor quadratic interaction V = ma² (OR - PR+a)². (a) Estimate the amplitude of zero-point fluctuations using the uncertainty principle, to show that, if ħ mwa² Scr where 5c is a dimensionless number of order one, the crystal will be unstable, even at absolute zero, and will melt due to zero-point fluctuations. (Hint: what would the answer be for a simple harmonic oscillator?) (b) Calculate e in the above model. If you like, to start out imagine that the atoms only move in one direction, so that is a scalar displacement at the site with equilibrium position R. Calculate the RMS zero-point displacement of an atom, √(01(x)²10). Now generalize your result to take account of the fluctuations in three orthogonal directions. (c) Suppose h/kB = 300K and the atom is a helium atom. Assuming that wis independent of atom separation a, estimate the critical atomic separation ac at which the solid becomes unstable to quantum fluctuations. Note that in practice w is dependent on a, and rises rapidly at short distances, with ~ a aa, where a> 2. Is the solid stable for a <ae or for a > ac? (2.151) According to the Lindeman criterion, a crystal melts when the RMS dis- placement of its atoms exceeds one-third of the average separation of the atoms. Consider a three-dimensional crystal with separation a, atoms of mass m and a nearest-neighbor quadratic interaction V = ma² (OR - PR+a)². (a) Estimate the amplitude of zero-point fluctuations using the uncertainty principle, to show that, if ħ mwa² Scr where 5c is a dimensionless number of order one, the crystal will be unstable, even at absolute zero, and will melt due to zero-point fluctuations. (Hint: what would the answer be for a simple harmonic oscillator?) (b) Calculate e in the above model. If you like, to start out imagine that the atoms only move in one direction, so that is a scalar displacement at the site with equilibrium position R. Calculate the RMS zero-point displacement of an atom, √(01(x)²10). Now generalize your result to take account of the fluctuations in three orthogonal directions. (c) Suppose h/kB = 300K and the atom is a helium atom. Assuming that wis independent of atom separation a, estimate the critical atomic separation ac at which the solid becomes unstable to quantum fluctuations. Note that in practice w is dependent on a, and rises rapidly at short distances, with ~ a aa, where a> 2. Is the solid stable for a <ae or for a > ac? (2.151)
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Related Book For
Campbell Biology
ISBN: 978-0321775658
10th edition
Authors: Jane B. Reece, Lisa A. Urry, Michael L. Cain, Steven A. Wasserman, Peter V. Minorsky, Robert B. Jackson
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